Aquatic and surface photochemistry

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書誌事項

Aquatic and surface photochemistry

edited by George R. Helz, Richard G. Zepp, Donald G. Crosby

Lewis Publishers, c1994

  • (acid-free paper)

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Aquatic and Surface Photochemistry provides a broad overview of current research in the emerging field of environmental aquatic and surface photochemistry. Selected reviews and current research articles are blended to provide an in-depth treatment of various aspects of this research area. The first part of the text deals with photochemistry in the environment, covering recent research on the following topics: aquatic photochemistry of organic pollutants and agrochemicals, photochemical cycling of carbon and transition metals (especially iron), photochemical formation of reactive oxygen species in natural waters, photoreaction in cloud and rain droplets, and photoreactions on environmental surfaces (soil, ash, metal, oxide). The second part provides discussions and data on both heterogeneous photocatalytic and homogeneous processes, with topics ranging from applications to mechanistic studies. These chapters illustrate the wide diversity of pollutant classes that are degradable by photochemical techniques and the effects of various reaction conditions on the rates and efficiency of the techniques. Current kinetic studies are presented, which provide new information about the role of adsorption and the nature of the reactive oxidizing species that mediate these photoremediation processes. This book will interest civil, chemical, and environmental engineers, as well as chemists, soil scientists, geochemists, and atmospheric chemists.

目次

Photochemistry in the Environment A Review of the Photochemical Redox Reactions of Iron (III) Species in Atmospheric, Oceanic, and Surface Waters: Influences on Geochemical Cycles and Oxidant Formation, B.C. Faust Photoredox Transformations of Iron and Manganese in Marine Systems: Review of Recent Field Investigations, T.D. Waite and R. Szymczak Photoredox Reactions at the Surface of Iron (III) (Hydr)Oxides, B. Sulzberger, H. Laubscher, and G. Karametaxas Photochemical Reactions in Atmospheric Waters: Role of Dissolved Iron Species, J. Hoigne, Y. Zuo, and L. Nowell A Temperature-dependent Competitive Kinetics Study of the Aqueous-phase Reactions of OH Radicals with Formate, Formic Acid, Acetate, Acetic Acid, and Hydrated Formaldehyde, M. Chin and P.H. Wine Factors Affecting Photolysis of Organic Compounds on Soils, G.C. Miller and S.G. Donaldson Recent Advances in the Photochemistry of Natural Dissolved Organic Matter, W.L. Miller Organic Dyes Bound to Polyelectrolytes: Photophysical Probes of Binding Domains and Biopolymer Conformation, G. Jones, II, C. Oh, and G.L. Indig Photochemical Degradation of Triazine and Anilide Pesticides in Natural Waters, F.H. Frimmel and D.P. Hessler The Relationship of Hydroxyl Reactivity to Pesticide Persistence, S.A. Mabury and D.G. Crosby Effect of Some Natural Photosensitizers on Photolysis of Some Pesticides, R. Tsao and M. Eto Sorption and Photochemical Transformation of Polycyclic Aromatic Compounds on Coal Stack Ash Particles, E.L. Wehry and G. Mamantov Photodehalogenation of 1,2,3,4-Tetrachlorodibenzo-p-Dioxin, P.K. Freeman and S.A. Hatlevig Photoinduced Reactions on Clay and Model Systems, X. Liu, K.-K. Iu, Y. Mao, and J.K. Thomas Anthracene Photochemistry in Aqueous and Heterogeneous Media, M.E. Sigman and S.P. Zingg Hydrogen Peroxide Formation and Decay in Lake Waters, D.R.S. Lean, W.J. Cooper, and F.R. Pick Singlet Oxygen Formation in Lake Waters from Mid-Latitudes, C. Shao, W.J. Cooper, and D.R.S. Lean Aqueous-Phase Photochemical Formation of Peroxides in Authentic Cloud Waters, C. Anastasio, J.M. Allen, and B.C. Faust Aqueous-Phase Photochemical Formation of Peroxyl Radicals and Singlet Molecular Oxygen in Cloud Water Samples from across the United States, J.M. Allen and B.C. Faust Examining the Role of Singlet Oxygen in Photosensitized Cytotoxicity, T.A. Dahl Photochemistry in Water Treatment Photocatalytic Treatment of Waters, D. Bahnemann, J. Cunningham, M.A. Fox, E. Pelizzetti, P. Pichat, and N. Serpone Adsorption of Model Pollutants onto TiO2 Particles in Relation to Photoremediation of Contaminated Water, J. Cunningham, G. Al-Sayyed, and S. Srijarani Photocatalytic Detoxification of Polluted Aquifers: Novel Catalysts and Solar Applications, D.W. Bahnemann, D. Bockelmann, R. Goslich, and M. Hilgendorff Heterogeneous Photocatalysis: Use in Water Treatment and Involvement in Atmospheric Chemistry, C. Guillard, L. Amalric, J.-C. D'Oliveira, H. Delprat, C. Hoang-Van, and P. Pichat Photocatalyzed Destruction of Water Contaminants: Mineralization of Aquatic Creosote Phenolics and Creosote by Irradiated Particulates of the White Paint Pigment Titania, N. Serpone, R. Terzian, D. Lawless, and A.-M. Pelletier Mechanistic Studies of Chloro- and Nitrophenolic Degradation on Semiconductor Surfaces, K.A. Gray, P. Kamat, U. Stafford, and M. Dieckmann Spin-Trap EPR Studies of Intermediates Involved in Photodegradation Reactions on TiO2: Is the Process Heterogeneous or Homogeneous?, L. Sun, K.-M. Schindler, A.R. Hoy, and J.R. Bolton Phenol and Nitrophenol Photodegradation Using Aqueous TiO2 Dispersions, A. Sclafani, L. Palmisano, and M. Schiavello Accelerated Photooxidative Dissolution of Oil Spills, A. Heller and J.R. Brock Photosensitization of Semiconductor Colloids by Humic Substances, K. Vinodgopal and P.V. Kamat The Role of Support Material in the Photodegradation of Colored Organic Compounds, P.V. Kamat and K. Vinodgopal Hydrogen Peroxide in Heterogeneous Photocatalysis, E.J. Wolfrum and D.F. Ollis Homogeneous Photodegradation of Pollutants in Contaminated Water: An Introduction, J.R. Bolton and S.R. Cater Determination of Rate Constants for Reactive Intermediates in the Aqueous Photodegradation of Pollutants Using a Spin-Trap/EPR Method, A.R. Hoy and J.R. Bolton Reaction Pathways in Advanced Oxidation Processes, C.C.D. Yao and T. Mill Photooxidation of Organic Compounds in Water and Air Using Low-Wavelength Pulsed Xenon Lamps, W.R. Haag Index

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