書誌事項

The Anomeric effect and associated stereoelectronic effects

Gregory R.J. Thatcher, editor

(ACS symposium series, 539)

American Chemical Society, 1993

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注記

"Developed from a symposium sponsored by the Division of Carbohydrate Chemistry at the 204th National Meeting of the American Chemical Society, Washington, DC, August 23-28, 1992."

Includes bibliographical references and indexes

内容説明・目次

内容説明

This volume was developed from a symposium sponsored by the Division of Carbohydrate Chemistry at the 204th National Meeting of the American Chemical Society held in Washington DC, from August 23-28, 1992. Highlights of the book: discuss contemporary experimental and computational studies on the anomeric effect; present conflicting data and theories in the controversial area; discuss applications in carbohyrate and organometallic chemistry, as well as applications for derivatives of sulfur and phosphorus oxyacids; and include a discussion of molecular modelling methods in compounds influenced by stereoelectronic effects.

目次

  • Anomeric effect - how it came to be postulated, John T. Edward
  • anomeric and associated stereoeleconic effects - scope and controversy, Gregory R.J. Thatcher
  • intramolecular strategies and stereoelectronic effects - glycosides and orthoesters hydrolysis revisited, P. Deslongchamps
  • anomeric and gauche effects - some basic stereoelectronics, Anthony J. Kirby and Nicholas H. Williams
  • anomeric effects - an iconoclastic view, Charles L. Perrin
  • no kinetic anomeric effect in reactions of acetal derivatives, Michael L. Sinnott
  • involvement of ns interactions in glycoside cleavage, C. Webster Andrews et al
  • X-C-Z anomeric effect and Y-C-C-Z gauch effect (X,Y = O,S
  • Z = O,N) - evaluation of the steric, electrostatic and orbital interaction components, B. Mario Pinto and Ronald Y.N. Leung
  • origin and quantitative modeling of anomeric effect, Peter A. Petillo and Laura E. Lerner
  • application of quantum theory of atoms in molecules to study of anomeric effect in dimethoxymethane, N.H. Westiuk et al
  • anomeric and reverse anomeric effect in acetals and related functions, F. Grein
  • glycosylmanganese complexes and anomeric anomalies - the next generation?, Philip DeShong et al
  • do stereoelectronic effects control the structure and reactivity of trigonal- bipyramidal phosphoesters?, Philip Tole and Carmay Lim
  • steroelectronic effects in pentaoxysulfuranes - putative intermediates in sulfuryl-group transfer, Dale R. Cameron and Gregory R.J. Thatcher
  • O-C-N anomeric effect in nucleosides - a major factor underlying the experimentally observed eastern barrier to pseudorotation, Ravi K. Jalluri.

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詳細情報

  • NII書誌ID(NCID)
    BA23538869
  • ISBN
    • 0841227292
  • LCCN
    93034423
  • 出版国コード
    us
  • タイトル言語コード
    eng
  • 本文言語コード
    eng
  • 出版地
    Washington, DC
  • ページ数/冊数
    xi, 305 p.
  • 大きさ
    24 cm
  • 分類
  • 件名
  • 親書誌ID
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