Advances in dendritic macromolecules
著者
書誌事項
Advances in dendritic macromolecules
JAI Press, 1994-
- vol. 1
- vol. 2
- vol. 3
- vol. 4
大学図書館所蔵 件 / 全10件
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vol. 1547.84||N 680000238846,
vol. 2547.84||N 680000238847, vol. 3547.84||N 680000238848, vol. 4547.84||N 680000238849 -
vol. 1431.9-N68-1100993011219,
vol. 2431.9-N68-2100993011226, vol. 3431.9-N68-3100993011233 -
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内容説明・目次
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vol. 3 ISBN 9780762300693
内容説明
The series Advances in Dendritic Macromolecules aims to cover the synthesis and supramolecular chemistry of dendritic or cascade super-molecules as well as their less perfect hyperbranched cousins.In Volume 3, Chapter 1 describes the synthesis and characterization of dendrimers and hyperbranched polyesters, both based on 2,2-bis(hydroxymethyl)propionic acid, as the AB2-monomer. Chapter 2, discusses the advantages and drawbacks of dendritic molecular architectures necessary to create polymeric organic magnetic materials. In Chapter 3, Balzani and colleagues delineate their contributions to the field of polynuclear transition metal complexes in the design and construction of dendritic nanostructures; these luminesence and redox-active complexes suggest their role as photochemical molecular devices operating by photoinduced energy and electron transfer processes. Chapter 4, reviews the overall progress on redox-active dendrimers, especially as redox catalysts, organic conductors, modified electrodes, and models for electron transfer proteins. Chapter 5, summarizes the pioneering research in organometallic dendritic macromolecules and then delineates the redox properties of a series of silicon-based ferrocenyl-containing dendrimers.
目次
Chapter headings. Preface. Dendrimers and hyperbranched aliphatic polyesters based on 2,-2Bis(hydroxymethyl) propionic acid (Bis-MPA). Consequences of the fractal character of dendritic high-spin macromolecules on their physiochemcial properties. Dendrimers based on metal complexes. Redox-active dendrimers, related building blocks, and oligomers. Organometallic dendritic macromolecules: organosilicon and organometallic entities as cores or building blocks. Index.
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vol. 4 ISBN 9780762303472
内容説明
The series Advances in Dendritic Macromolecules aims to cover the synthesis and supramolecular chemistry of dendritic or cascade super-molecules as well as their less perfect hyperbranched cousins.
The field of hyperbranched macromolecules, specifically dendrimers, has continued to expand at an amazing rate. The synthetic aspects, which were assumed to be over several years ago, have opened new avenues into the mesomolecular regime. The synthetic ingenuity of chemical artists has afforded new monomers and their diverse combinations to give rise to (poly)functionalized materials that embrace new supramolecular concepts in areas such as molecular recognition, assembly, encapsulation, and inclusion; catalysts; coatings; drug delivery systems; and in essence opens up the field of suprasupermolecular chemistry.
In chapter 1 the synthesis of organometallic and related transition metal-cotaining dendrimers is summarized and their novel properties and useful applications are described. Chapter 2 covers work on the commercial poly(propylene imine)s, including the "dendritic box", dendrimer-based superamphiphiles, and unimolecular inverse micelles. The next chapter looks at aspects of chirality in dendritic systems and this is followed by a look inside dendrimers from a molecular topologist's point-of-view.
目次
Introduction. Organometallic dendrimers: synthesis, structural aspects, and applications in catalysis. Poly(propylene imine) dendrimers. Chiral dendrimers. Molecular topology of dendrimers. Index.
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vol. 1 ISBN 9781559386968
内容説明
The series Advances in Dendritic Macromolecules aims to cover the synthesis and supramolecular chemistry of dendritic or cascade super-molecules as well as their less perfect hyperbranched cousins.
In volume 1 of the series, Chapter 1 presents an overview of the current synthetic methodology available through mid-1993 for the preparation of cascade/dendritic macromolecules. Chapter 2 deals with the pioneering work of and by Professor Moore and his group in the construction of stiff dendritic macromolecules based on phenylacetylenes. The preparation and properties of monodisperse aromatic dendrimers by Neenan, Miller, and collaborators are reviewed in Chapter 3. Chapter 4, describes work in the generation of high-spin polyarylmethyl polyradicals. To address one of the serious retrieval and descriptive problems associated with these specific polymers, in Chapter 5, Baker and Young present a systematic nomenclature for cascade (dendritic) polymers.
目次
Chapter headings. Introduction to the series: An editor's foreword. Preface. A review of dendritic macromolecules. Stiff dendritic macromolecules based on phenylacetylenes. Preparation and properties of monodisperse aromatic dendritic macromolecules. High-spin polyarylmethyl polyradicals. A systematic nomenclature for cascade (dendritic) polymers. Index.
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vol. 2 ISBN 9781559389396
内容説明
The series Advances in Dendritic Macromolecules aims to cover the synthetic, as well as chemical, aspects of this expanding field: the chemistry to and supramolecular chemistry of dendritic or cascade supermolecular compounds. In Chapter 1 of this volume, Hawker and Wooley delineate the convergent growth approach to dendrimers, then relate their three-dimensional architectures to different block polymers. In Chapter 2, Moors and Voegtle describe Professor Voegtle's initial cascade molecules via the repetitive strategy, then expand his original concepts of its application by others, and lastly delineate the synthesis of a new series of tosylamide cascades. They also demonstrate the utility of his original Michael addition/reduction procedure by its application to differ cores. Chapter 3, composed by Professor Engel, describes ionic dendrimers which incorporated an internal transition metal center as well as his work based on ammonium and phosphonium centers. In Chapter 4, Mathias and Carothers review recent studies on silicon-based dendrimers and hyperbranched polymers. Chapter 5, by Kim, describes the preparation and utility of hyperbranched aromatic polymers. Lastly in Chapter 6, Escamilla reviews the historical as well as recent examples of ionic and nonionic bolaamphiphiles.
目次
Chapter headings. Preface. The convergent-growth approach to dendritic macromolecules. Cascade molecules: building blocks, multiple functionalization, complexing units, photo-switching. Ionic dendrimers and related materials. Silicon-based stars, dendrimers, and hyperbranched polymers. Highly branched aromatic polymers: their preparation and applications. Dendritic bolaamphiphiles and related molecules. Index.
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