The anomeric effect
著者
書誌事項
The anomeric effect
（New directions in organic and biological chemistry）
CRC Press, c1995
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
This book provides a comprehensive review of the structural, conformational, and chemical manifestations of the anomeric effect. In order to present a cogent discussion of this most fundamental and relevant phenomenon, three chapters examine our present understanding of the origin of this conformational effect, based upon a wealth of theoretical and physical data. Equally important, however, are three additional chapters that deal with the general consequences of the stereoelectronic interactions that are associated with the basis of the anomeric effect. The remainder of the book is devoted to new areas of development in the topic-such as differentiation of the endo and exo anomeric interactions, specific analysis of the enthalpic component of anomeric effects, critical evaluation of the kinetics and reverse anomeric effects, discovery of a new substantial effect in second- and lower-row anomeric segments, and others.
目次
Historical Aspects and Definitions
Origin and Consequences of the Anomeric Effect
Theoretical Studies of the Anomeric Effect
Stereoelectronic Effects Associated with the Anomeric Effect
Endo and Exo Anomeric Interactions
The Enthalpic Anomeric Effect
Second- and Lower-Row Anomeric Interactions
The Reverse Anomeric Effect
The Kinetic Anomeric Effect
Applications of the Anomeric Effect in Organic Synthesis
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