Metalloporphyrins in catalytic oxidations
著者
書誌事項
Metalloporphyrins in catalytic oxidations
Marcel Dekker, c1994
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
This volume provides an in-depth overview of the chemistry of metalloporphyrins as oxidation catalysts in chemical and biological systems. It discusses practical techniques for the synthesis of metalloporphyrins and introduces useful methods of immobilization to improve their synthetic utility. Detailed discussions of underlying mechanistic features are provided.
目次
- Oxidation Catalysis by Metalloporphyrins - A Historical Perspective
- The Mechanisms of Reaction of Hypervalent Oxochromium, Iron and Manganese Tetraphenylporphyrins with Alkenes
- Theoretical Studies of Oxometalloporphyrins and Their Reactions with Organic Substrates
- Cytochrome P450 Model Systems
- Heme Proteins in Prostaglandin Biosynthesis
- Synthetic Aspects of Porphyrin and Metalloporphyrin Chemistry
- Asymmetric Oxidation with Chiral Metalloporphyrin Catalysts
- Metalloporphyrin-Catalyzed Oxidation of Hydrocarbons with Dioxygen
- Reactions of Alkanes with Dioxygen - Toward Suprabiotic Systems
- Supported Metalloporphyrin Models for Heme-Catalyzed Oxidations
- Epilogue - Future Prospects.
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