Optical polarization of molecules

書誌事項

Optical polarization of molecules

Marcis Auzinsh, Ruvin Ferber

(Cambridge monographs on atomic, molecular, and chemical physics, 4)

Cambridge University Press, 1995

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注記

Includes bibliographical references

内容説明・目次

内容説明

This book explains the theory and methods by which gas molecules can be polarized by light, a subject of considerable importance for what it tells us about the electronic structure of molecules and properties of chemical reactions. Starting with a brief review of molecular angular momentum, the text goes on to consider resonant absorption, fluorescence, photodissociation and photoionization, as well as collisions and static fields. A variety of macroscopic effects are considered, among them angular distribution and the polarization of emitted light, ground state depopulation, laser-induced dichroism, the effect of collisions and external magnetic and electric field effects. Most examples in the book are for diatomic molecules, but symmetric-top polyatomic molecules are also included. The book concludes with a short appendix of essential formulae, tables for vector calculus, spherical functions, Wigner rotation matrices, Clebsch-Gordan coefficients, and methods for expansion over irreducible tensors.

目次

  • 1. Angular momentum and transition dipole moment
  • 2. Excited state angular momenta distribution
  • 3. Ground state angular momenta polarization
  • 4. Effect of external magnetic field on angular momenta distribution
  • 5. General equations of motion for arbitrary J values
  • 6. Other methods of alignment and orientation of molecules
  • Appendix
  • References
  • Index.

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