Crown ethers and cryptands
著者
書誌事項
Crown ethers and cryptands
（Monographs in supramolecular chemistry, no. 3）
Royal Society of Chemistry, c1994
- : pbk
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注記
1st pub. in hardback 1991
内容説明・目次
内容説明
A monograph which attempts to give the beginner or generalist some perspective on the field of crown ethers and cryptands and its early development. It also tries to give a notion of syntheses, binding phenomena, complex structures, and to offer a representative sample of applications.
目次
- Part 1 Introduction to macrocycle chemistry: crown ether precursor work
- Pedersen's discovery of crown ethers
- Simmons' in-out bicyclic amines
- Lehn's cryptands
- cram and carbanions
- classes of crown ethers and cryptands
- naturally occurring relatives of crown ethers
- nomenclature and its problems
- toxicity of crown ether compounds. Part 2 Syntheses of crowns, cryptands and their relatives: Pedersen's first crowns
- the ethylencoxy structural unit
- the template effect
- early syntheses of crowns
- syntheses of crown ethers
- incorporation of aromatic subunits
- nitrogen-containing macrocycles
- crown ethers containing sulfur
- syntheses of cryptands
- spherands, cavitands, and carcerands. Part 3 Complexation by crowns and cryptands: the extraction technique
- homogeneous cation binding constants
- binding dynamics
- cation transport
- complexation of organic cations
- anions. Part 4 Structural aspects of crowns, cryptands, and their complexes: uncomplexed crown and cryptand ligands
- simple crown ether complexes of metal cations
- complexes of cryptands
- crown ether complexes of other ions and molecules
- podand complexes. Part 5 Applications of crowns and cryptands: solubilization phenomena
- cation deactivation
- anion activation - phase transfer catalysis
- sensors and switching
- polymeric crown systems
- membranes and channels
- chirality, complexation and enzyme models
- receptor molecules
- miscellaneous applications and developments
- the future of crown ether chemistry. Part 6 Additional reading: books crown ethers cryptands, and polyethers
- monographs on phase transfer catalysis
- reviews and articles.
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