Carbon-13 NMR chemical shifts in structural and stereochemical analysis

Bibliographic Information

Carbon-13 NMR chemical shifts in structural and stereochemical analysis

Kalevi Pihlaja and Erich Kleinpeter

(Methods in stereochemical analysis)

VCH, c1994

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Includes bibliographical references and index

Description and Table of Contents

Description

This text concentrates on illustrating the applications of C-13 chemical shifts to structural and stereochemical analysis of a variety of organic, organometallic and bio-organic compounds, including dynamic NMR, the experimental conditions to determine and various multidimension methods to assign the C-13 chemical shifts. The book is limited mainly to alicyclic chemistry in order to make the explanations accessible to readers. This work is aimed at structural chemists, organic chemists, spectroscopists, instructors in the chemical industry and lecturers in chemistry.

Table of Contents

  • Substituent effect correlations
  • on the origin and stereochemical connections of the substituent effects
  • conformational and configurational analysis and substituent effects on the 13C NMR chemical shifts of alicyclic compounds
  • structural and stereochemical analysis of four- and five-, and seven-membered cyclanes and some other systems
  • on the origin of stereoelectronic substituent effects
  • 13C chemical shifts as probes in configurational and conformational analysis
  • dynamic NMR spectroscopy and frozen spectra
  • application of 13C NMR spectroscopy to the configurational and conformational analysis of natural products, organometallic compounds, and synthetic polymers
  • application of other NMR parameters in combination with the 13C chemical shift in conformational and configurational analysis.

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