Container molecules and their guests
著者
書誌事項
Container molecules and their guests
（Monographs in supramolecular chemistry, 4）
Royal Society of Chemistry, c1994
- :pbk
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内容説明・目次
- 巻冊次
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ISBN 9780851869728
内容説明
This volume covers the evolution of host-guest complexation chemistry in the minds of Nobel Prize-winner Donald Cram and his co-workers at UCLA, over the period from 1970-1994. It deals with the fundamental principles and objectives that govern this rapidly developing subject and illustrates the emergence of a new field of biomimetic chemistry. The book demonstrates how a number of techniques, such as molecular modelling, synthesis, crystal structure, NMR solution structure and mass spectral structure determinations can be combined to develop a new branch of organic chemistry. It discusses the chemistry of completely new families of complexes - the carceplexes, hemicarceplexes and velcraplexes - and reviews the uses of the interiors of hemicarceplexes as a new phase for carrying out chemical reactions and for protecting unstable species. The volume illustrates how complexation and decomplexation rates are measured to provide free energies of binding, discusses new phenomena such as constrictive binding, and shows how solvophobic forces drive complexation in a variety of organic solvents.
It also covers catalysis through complexation and chiral recognition in catalysis, both secondary themes of this volume.
目次
- Contexts, conceptions, corands and coraplexes
- spherands, spheraplexes and their relatives
- chiral recognition in complexation
- partial enzyme mimics
- cavitands
- vases, kites, velcrands and velcraplexes
- carcerands and carceplexes
- hemicarcerands and constrictive binding
- varieties of hemicarcerands
- reactions of complexes hosts, of incarcerated guests and hosts protection of guests from self-destruction.
- 巻冊次
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:pbk ISBN 9780854045075
内容説明
Container Molecules and Their Guests deals with the fundamental principles and objectives that govern this rapidly developing subject and illustrates the emergence of a new field of biomimetic chemistry. The book demonstrates how a number of techniques, such as molecular modelling, synthesis, crystal structure, NMR solution structure and mass spectral structure determinations can be combined to develop a new branch of organic chemistry. It discusses the chemistry of completely new families of complexes - the carceplexes, hemicarceplexes and velcraplexes - and reviews for the first time the uses of the interiors of hemicarceplexes as a new phase for carrying out chemical reactions and for protecting unstable species. Furthermore, it illustrates how complexation and decomplexation rates are measured to provide free energies of binding, discusses new phenomena such as constrictive binding, and shows how solvophobic forces drive complexation in a variety of organic solvents. It also covers catalysis through complexation and chiral recognition in catalysis, both secondary themes of this volume. Container Molecules and Their Guests will provide stimulating reading for researchers, post-graduate students and teachers involved in bio-organic chemistry, organic chemistry, materials science, and medicinal and pharmaceutical chemistry.
目次
- Contexts, Conceptions, Corands, and Coraplexes
- Spherands, Spheraplexes, and Their Relatives
- Chiral Recognition in Complexation
- Partial Enzyme Mimics
- Cavitands
- Vases, Kites, Velcrands, and Velcraplexes
- Carcerands and Carceplexes
- Hemicarcerands and Constrictive Binding
- Varieties of Hemicarcerands
- Reactions of Complexed Hosts, of Incarcerated Guests, and Hosts Protection of Guests from Self Destruction
- Subject Index.
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