Organosulfur chemistry
著者
書誌事項
Organosulfur chemistry
Academic Press, c1995-
- [v. 1]
- v. 2
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注記
[v. 1]. Synthetic aspects -- v. 2. Synthetic and stereochemical aspects
Includes bibliographies and indexes
内容説明・目次
- 巻冊次
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[v. 1] ISBN 9780125435604
内容説明
During the last few years, the impact of organosulfur chemistry, especially in the areas of stereocontrolled processes, has led to an explosion of interest in the field. This book is intended to provide in-depth coverage of topics of interest throughout the whole range of organic sulfur chemistry, including bio-organic, physical organic, and synthetic aspects.
目次
G. Solladie and M.C. Carreto, Optically Active Beta-keto Sulfoxides and Analogues in Assymetric Synthesis. Introduction. Homochiral Sulfoxide Preparations: the Andersen Approach. Stereoselective Reduction of Beta-keto Sulfoxides. Application of the Beta-keto Sulfoxide Reduction to Total Synthesis. Diels-Alder Reactions to Alkenyl Sulfoxides as Dienophiles. Diels-Alder Reactions of Sulfinyldienes. D. Crich, Homolytic Processes at Sulfur in Synthesis. Introduction. Reactions of Sulfur-Centered Radicals. Generations of Alkyl Radicals from Organosulfur Groups. Formation of Carbon-Sulfur Bonds by Reaction of Carbon-Centered Radicals with Sulfur Functional Groups. C.M. Rayner, Synthetic Transformations Involving Thiiranium Ion Intermediates. Reviews. General Considerations. Synthesis of Thiiranium Ion. Reactions of Thiiranium Ions. Summary. W.W. Wood, Trends in the Chemistry of 1,3-Dithioacetals. Introduction. Applications of Dithioacetals in Biological Effect Molecules. Synthesis of 1,3- Dithioacetals. Chemistry of 1,3- Dithioacetals. 1,3- Dithioacetal as a Functional Group. R. Okazaki, Chemistry of Thioaldehydes. Introduction. Transient Thioaldehydes. Stable Thioaldehydes.
- 巻冊次
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v. 2 ISBN 9780125435628
内容説明
The impact of organosulfur chemistry, especially in the areas of heterocyclic chemistry, stereocontrolled processes, and asymmetric synthesis, has led to a resurgence of interest in the field. This book is the secondin a series intended to provide coverage of topics of current interest throughout the whole range of organosulfur chemistry. Each volume is comprised of five or six chapters, each consisting of an in-depth, self-contained review in a well-defined area. This volume and its predecessor Organosulfur Chemistry, Synthetic Aspects will prove valuable references for researchers and practitioners in organic chemistry.
目次
- Asymmetric sulphoxidation - chemical and enzymatic, H.B. Kagan and P. Diter
- the synthesis of chiral sulphoxides through nucleophilic displacement at sulphur, S.M. Allin and P.C. Bulman Page
- conformational preference of the sulphinyl group in six-membered heterocycles, E. Juaristi and M. Ordonez
- applications of chiral sulphoxides as stereocontrol elements in organic sythesis, S.M. Allin, S.J. Shuttleworth and P.C. Bulman Page
- preparation of substituted 3-sulpholenes and their use as precursors for diels-alder dienes, J. Leonard, A.B. Hague and J.A. Knight.
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