Modern acetylene chemistry
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書誌事項
Modern acetylene chemistry
VCH, 1995
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注記
Bibliography: p. 469-471
内容説明・目次
内容説明
Acetylene chemistry has many industrially important applications in the field of chemistry. Each chapter in this text presents experimental protocols for practical laboratory work and should be of interest to organic and organometallic chemists.
目次
- Part 1 Modern computational and theoretical aspects of acetylene chemistry, Dietmar A. Plattner et al: electronic structures of acetylene and monoacetylenes
- reactivities and molecular interactions of acetylenes
- polyacetylenes. Part 2 Functionalized acetylenes in organic synthesis - the cases of the 1-cyano- and the 1-halogenacetylenes, Henning Hopf and Bernhard Witulski: synthesis and preparative use of cyanoacetylenes
- synthesis and preparative use of 1-halogenacetylenes
- experimental procedures. Part 3 Alkynyliodonium salts - electrophilic acetylene equivalents, Peter J. Stang: preparation and properties
- characterization and structure
- reactions and uses of alkynyliodonium salts
- experimental procedures. Part 4 The chemistry of metal-alkyne complexes, Gagik G. Melikyan and Kenneth M. Nicholas: bonding and structure
- complexes of novel alkynes
- reactions of metal-alkyne complexes
- special applications of metal-alkyne complexes
- selected experimental procedures. Part 5 Organometallic cycloaddition reactions of acetylenes, Joseph A. Casalnuovo and Neil E. Schore: cycloadditions of acetylenes with Fischer carbenes
- the Pauson-Khand reaction - cycloadditions of olefins, acetylenes and CO. Part 6 Phosphaalkynes - starting point for the synthesis of phosphorous-carbon cage compounds, Manfred Regitz et al: syntheses of phosphaalkynes
- reactivity of phosphaalkynes
- the history of phosphorous-carbon cage compounds from phosphaalkynes
- synthesis of phosphorous-carbon cage compounds
- outlook
- experimental procedures. Part 7 The enediyne antibiotics, K.C. Nicolaou and Adrian L. Smith: the aromaticity era
- the discovery of the enediyne antibiotics
- theoretical and synthetic studies on the enediyne antibiotics
- medical applications of the enediyne antibiotics. Part 8 Cyclic alkynes - preparation and properties, Rolf Gleiter and Roland Merger: synthesis of cyclic acetylenes
- structural and spectroscopic properties
- organic reactions of cyclic alkynes
- reactions of cyclic alkynes with metal compounds
- experimental procedures. Part 9 Macrocyclic homoconjugated polyacetylenes, Lawrence T. Scott and Mark J. Cooney: pericyclynes
- "exploded" pericyclynes
- homoconjugated mixed polyalkyne/diyne macrocycles
- heterocyclic cognates of pericyclynes
- experimental procedures. Part 10 Polyacetylene, Eric J. Ginsburg et al: syntheses and properties. Part 11 Acetylenic compounds as building blocks for high-spin molecules and molecular assemblies, Hiizu Iwamura and Kenji Matsuda: alkynyl compounds carrying unpaired electrons
- molecular crystals of organic free radicals that carry alkynyl substituents
- spin alignments in poly(phenylacetylenes) and poly(1,3-butadiynes)
- cyclotrimerization reaction of benzoylacetylenes in the presence of a secondary amine
- experimental procedures. Part 12 Acetylenes in nanostructures, James K. Young and Jeffrey S. Moore: phenylacetylene dendrimers
- phenylacetylene macrocycles
- synthesis of sequence-(Part contents)
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