Multiply bonded main group metals and metalloids
著者
書誌事項
Multiply bonded main group metals and metalloids
（Advances in organometallic chemistry / edited by F.G.A. Stone, Robert West, v. 39）
Academic Press, c1996
- : pbk. alk. paper
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注記
Includes bibliographical references and index
内容説明・目次
- 巻冊次
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ISBN 9780120311392
内容説明
This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.
目次
P.J. Brothers and P.P. Power, Multiple Bonding Involving the Heavier Main Group 3 Elements Al, Ga, In, and Tl. A.G. Brook and M.A. Brook, The Chemistry of Silenes. I. Hemme and U. Klingebiel, Iminosilanes andRelated Compounds--Synthesis and Reactions. M. Driess, Silicon Phosphorus and Silicon Arsenic Multiple Bonds. R. Okazaki and R. West, Chemistry of Stable Disilenes. K.M. Baines and W.G. Stibbs, Stable Doubly Bonded Compounds ofGermanium and Tin. A.J. Ashe, III, and S. Al-Ahmad, Diheteroferrocenes and Related Derivatives of the Group 15 Elements: Arsenic, Antimony, and Bismuth. J.J. Eisch, Boron Carbon Multiple Bonds. Chapter References. Subject Index. Cumulative List of Contributors 1 36. Cumulative Index 37 39.
- 巻冊次
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: pbk. alk. paper ISBN 9780127447407
内容説明
This volume surveys major advances in the area of organometallic chemistry - the synthesis of stable, multiply bonded compounds of main group metals and metalloids. Notable advances occurred in this field in 1981, when the synthesis of stable compounds containing Si=C, Si=Si, and P-P multiple bonds were announced. Until these discoveries, organometallic chemistry had been limited by the double-bond rule, which asserted that elements outside the first row of the periodic table would not form stable multiple bonds. During the intervening 14 years, many other stable multiply bonded compounds have been discovered, and the field of organometallic chemistry has expanded as a result. This volume surveys the current knowledge of many of these compounds and should be of use to researchers and students in the field.
目次
- Multiple bonding involving heavier main group 3 elements Al, Ga, In, and TI, P.J. Brothers, P.P. Power
- The chemistry of silenes, A.G. Brook, M.A. Brook
- Iminosilanes and related compounds - synthesis and reactions, I. Hemmes, U. Klingebiel
- Silicon-phosphorus and silicon-arsenic multiple bonds, M. Driess
- Chemistry of stable disilenes, R. Okazaki, R. West
- Stable doubly-bonded compounds of germanium and tin, K. M. Baines, W.G. Stibbs
- Diheteroferrocenes and related derivatives of the group 15 elements: arsenic, antimony, and bismuth, A.J. Ashe III, S. Al-Ahmad
- Boron-carbon multiple bonds.
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