The chemistry of C-glycosides
著者
書誌事項
The chemistry of C-glycosides
(Tetrahedron organic chemistry series, v. 13)
Pergamon, c1995
- : pbk.
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
In recent years C-glycoside chemistry has been one of the main topics in carbohydrate chemistry, not only because of the synthetic challenges posed, but also because C-glycosides have the potential to serve as carbohydrate analogues resistant to metabolic processes. Consequently, this class of compounds is currently receiving much interest as a potential source of therapeutic agents for clinical use. This book provides a broad coverage of the various synthetic methods available for the preparation of C-glycosides, and illustrates the interesting breadth of connections between carbohydrate chemistry and modern general synthetic organic chemistry by including topics such as transition-metal catalysis, radical chemistry, cycloaddition and rearrangement processes. In addition, in the final chapter of the book, the syntheses of C-di and trisaccharides reported through 1994 are reviewed. This well organised account of the synthetic chemistry in this field will prove to be very valuable to a wide range of researchers and advanced students, both as an introduction to the topic and for reference.
目次
1. Electrophilic Substitutions
2. Nucleophilic Sugar Substitutions
3. Transition Metal Mediated C-Glycosidations
4. Anomeric Radicals
5. Rearrangements and Cycloadditions
6. Sugar Ring Formations
7. Syntheses of C-Di and Trisaccharides
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