Organometallic chemistry
著者
書誌事項
Organometallic chemistry
Prentice-Hall, c1997
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Addressing the need for an introductory Organometallic Chemistry text, Spessard and Miessler have combined numerous illustrations, problems and well-referenced coverage in an overall accessible approach to this subfield of Inorganic Chemistry.* Provides an early, comprehensive introduction to molecular orbital theory to lay a foundation for further emphasis on structure and bonding. * Features a unique way of categorizing organometallic reactions on the basis of whether actions are mainly at metal or at ligand. * Features in-depth coverage of reaction mechanisms. * Offers a thorough discussion of carbene chemistry allowing readers to focus on all aspects of metal carbenes in one chapter (Chapter 10). * Depicts numerous applications of organometallic chemistry including organic synthesis, lanthanide chemistry, and catalysis, showing students that the field is relevant and growing. * Constructs a strong pedagogical framework composed of worked examples, in-chapter as well as end-of-chapter problems, outstanding illustrations, and special-interest features.
目次
- 1. Overview of Organometallic Chemistry. Striking Difference. Historical Background. 2. Fundamentals of Structure and Bonding. Atomic Orbitals. Molecular Orbitals. 3. The 18-Electron Rule. Counting Electrons. Why 18 Electrons? Square Planar Complexes. 4. Carbonyl Ligand. Bonding. Binary Carbonyl Complexes. Oxygen-Bonded Carbonyls. Ligands Similar to CO. Infared Spectra. Main Group Parallels with Binary Carbonyl Complexes. 5. Pi Ligands. Linear Pi Systems. Cyclic Pi Systems. NMR Spectra of Organometallic Compounds. 6. Other Important Ligands. Complexes Containing M-C, M=C, and M...UEC Bonds. Hydride and Dihydrogen Complexes. Phosphines and Related Ligands. 7. Organometallic Reactions I: Reactions That Occur at the Metal. Ligand Substitution. Oxidative Addition. Reductive Elimination. 8. Organometallic Reactions II: Reactions Involving Modification of Ligands. Insertion and Deinsertion. Nucleophilic Addition to the Ligand. Nucleophilic Abstraction. Electrophilic Reactions. 9. Homogeneous Catalysis: Use of Transition Metal Complexes in Catalytic Cycles. Fundamental Concepts of Homogeneous Catalysis. Hydroformylation Reaction. Wacker-Smidt Synthesis of Acetaldehyde. Hydrogenation. Monsanto Acetic Acid Process. Future Directions for Transition Metal Catalysis. 10. Transition Metal-Carbene and Transition-Metal Carbyne Complexes: Structure, Preparation, and Chemistry
- Metathesis and Polymerization Reactions. Structure of Metal-Carbene Complexes. Synthesis of Metal-Carbene Complexes. Reactions of Metal-Carbene Complexes. Metal-Carbyne Complexes. Metathesis. Ziegler-Natta Polymerization of Alkenes. Sigma (...) Bond Metathesis. 11. Applications of Organometallic Chemistry to Organic Synthesis. Enantioselective Functional Group Interconversions. Organotransition Metal Complexes as Protecting and Activating Groups. Carbon-Carbon Bond Formation via Carbonyl and Alkene Insertion. Carbon- Carbon Bond Formation via Transmetallation Reactions. Carbon-Carbon Bond Formation through Cyclization Reactions. 12. Isolobal Groups and Cluster Compounds. Isolobal Analogy. Cluster Compounds. 13. Other Applications of Organometallic Chemistry: Bioorganometallic Chemistry, Organolanthanide Chemistry, Solid-State and Surface Chemistry, and Fullerene-Metal Complexes. Bioorganometallic Chemistry. Organolanthanide Chemistry. Surface Organometallic Chemistry. Fullerene-Metal Complexes. Appendix A: List of Abbreviations. Appendix B: Answers to Exercises. Index.
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