pH and buffer theory : a new approach

著者

    • Rilbe, H. (Harry)

書誌事項

pH and buffer theory : a new approach

H. Rilbe

(Wiley series in solution chemistry, v. 1)

Wiley, c1996

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注記

Includes bibliographical references (p. [183]-185) and indexes

内容説明・目次

内容説明

Volumes in the Wiley Series in Solution Chemistry cover experimental investigation, theoretical interpretation and prediction of physical chemical properties and behaviour of solutions. Industrial applications and environmental consequences of solution chemistry are also covered. The first volume in the series examines one of the central problems in chemistry, the accurate solution of very complex equations. Since speeds and types of reaction are usually governed by the pH of the reaction medium, a detailed, predictive theory is a central requisite of the field. The author has been a key figure in pH theory and solution chemistry. He and co-workers have been instrumental in developing a fully workable theory which both accommodates the results of experiment and provides a soluble, descriptive system of equations and graphs. This book demonstrably summarizes this effort, providing both new experimental methods and theoretical approach. The book is supported throughout by the use of experimental methods which verify the predictive theory. It should be of interest to postgraduate and industrial researchers in physical chemistry and chemical physics.

目次

  • Monovalent weak acids and bases and their salts with strong bases and acids
  • bivalent weak protolytes and their salts with strong acids and bases
  • binary mixtures of monovalent weak protolytes
  • tri and paucivalent weak protolytes and their salts with strong acids and bases
  • the Debye-Hnckel theory for strong electrolytes
  • the titration curve and the buffer power of water
  • experimental determination of pK and (pK values as well as Isoprotic points.

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