Reaction rates of isotopic molecules
著者
書誌事項
Reaction rates of isotopic molecules
(A Wiley-Interscience publication)
Wiley, c1980
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注記
Edition of 1960 published under title: Isotope effects on reaction rates
Includes bibliographical references and index
内容説明・目次
内容説明
Explains in terms of transition-state theory and simple models for tunneling why isotopic molecules react at different rates and how to measure these differences in experiments. Critically surveys a wide range of the more important, reliable experimental results and conclusions, demonstrating how kinetic isotope effects can be interpreted to give information of mechanistic value. Contains numerous examples from organic chemistry that feature techniques which are also applicable to inorganic chemistry and biochemistry.
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