Organic synthesis in water
著者
書誌事項
Organic synthesis in water
Blackie Academic & Professional, 1998
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注記
Includes index
内容説明・目次
内容説明
The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits, in both unique chemistry and reduced environmental impact. In this volume, the editor brings together an international team of authors, each taking advantage of the unique properties of water for carrying out organic transformations, in order to provide an overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, should find this book a useful guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, should find this book of interest.
目次
1. Diels-Alder reactions in aqueous media. 2. Hetero Diels-Alder reactions. 3. Claisen rearrangements in aqueous solution. 4. Carbonyl additions and organometallic chemistry in water. 5. Aqueous transition-metal catalysis. 6. Oxidations and reductions in water. 7. Base-catalyzed Aldol- and Michael-type condensations in aqueous media. 8. Water-stable rare-earth Lewis-acid catalysis in aqueous and organic solvents. 9. Organometallic chemistry in water. 10. Transition metal catalyzed carbon-carbon bond pairing reactions in water. Index.
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