内容説明
Organosilicon compounds are key organometallic compounds (R-Si)which have many uses in materials science and in metallurgy. Theirapplications include the synthesis of sugars and in the synthesisof organic compounds for the pharmaceutical industry. This volumewill contain both updated chapters on key topics included in theoriginal volumes as well as a number of new chapters reflecting therapid developments made in silicon chemistry and its applicationsto organometallic chemistry, materials science, and semiconductors,over the last five years. As for the majority of volumes in thisseries, chapters will be prepared by leading scientists in thefield.
This volume is now available in electronic format from BooksOnline.
目次
Theoretical Aspects and Quantum Mechanical Calculations ofSilaaromatic Compounds (Y. Apeloig & M. Karni).
A Molecular Modeling of the Bonded Interactions of CrystallineSilica (G. Gibbs & M. Boisen).
Polyhedral Silicon Compounds (A. Sekiguchi & S. Nagase).
Thermochemistry (R. Becerra & R. Walsh).
The Structural Chemistry of Organosilicon Compounds (M. Kaftory, etal.).
?29Si NMR Spectroscopy of Organosilicon Compounds (Y. Takeuchi& T. Takayama).
Activating and Directive Effects of Silicon (A. Bassindale, etal.).
Steric Effects of Silyl Groups (J. Hwu, et al.).
Reaction Mechanisms of Nucleophilic Attack at Silicon (A.Bassindale, et al.).
Silicenium Ions: Quantum Chemical Computations (C. Maerker & P.Schleyer).
Silicenium Ions: Experimental Aspects (P. Lickiss).
Silyl-Substituted Carbocations (H. Siehl & T. Muller).
Silicon-Substituted Carbenes (G. Maas).
Alkaline and Alkaline Earth Silyl Compounds--Preparation andStructure (J. Belzner & U. Dehnert).
Mechanism and Structures in Alcohol Addition Reactions of Disilenesand Silenes (H. Sakurai).
Silicon-Carbon and Silicon-Nitrogen Multiply Bonded Compounds (T.Muller, et al.).
Recent Advances in the Chemistry of Silicon-Heteroatom MultipleBonds (N. Tokitoh & R. Okazaki).
Gas-Phase Ion Chemistry of Silicon-Containing Molecules (N.Goldberg & H. Schwarz).
Matrix Isolation Studies of Silicon Compounds (G. Maier, etal.).
Electrochemistry of Organosilicon Compounds (T. Fuchigami).
The Photochemistry of Organosilicon Compounds (A. Brook).
Mechanistic Aspects of the Photochemistry of OrganosiliconCompounds (M. Kira & T. Miyazawa).
Hypervalent Silicon Compounds (D. Kost & I. Kalikhman).
Silatranes and their Tricyclic Analogs (V. Pestunovich, etal.).
Tris(Trimethylsilyl)Silane in Organic Synthesis (C. Chatgilialoglu,et al.).
Recent Advances in the Direct Process (L. Lewis).
Acyl Silanes (P. Page, et al.).
Recent Synthetic Applications of Organosilicon Reagents (E.Colvin).
Recent Advances in the Hydrosilylation and Related Reactions (I.Ojima, et al.).
Synthetic Applications of Allylsilanes and Vinylsilanes (T. Luh& S. Liu).
Chemistry of Compounds with Silicon-Sulphur, Silicon-Selenium andSilicon-Tellurium Bonds (D. Armitage).
Cyclic Polychalcogenide Compounds with Silicon (N. Choi & W.Ando).
Organosilicon Derivatives of Fullerenes (W. Ando & T.Kusukawa).
Group 14 Metalloles, Ionic Species and Coordination Compounds (J.Dubac, et al.).
Transition-Metal Silyl Complexes (M. Eisen).
Cyclopentadienyl Silicon Compounds (P. Jutzi).
Recent Advances in the Chemistry of Cyclopolysilanes (E. Hengge& H. Stuger).
Recent Advances in the Chemistry of Siloxane Polymers andCopolymers (R. Drake, et al.).
Si-Containing Ceramic Precursors (R. Laine & A.Sellinger).
Organo-Silica Sol--Gel Materials (D. Avnir, et al.).
Chirality in Bioorganosilicon Chemistry (R. Tacke & S.Wagner).
Highly Reactive Small-Ring Monosilacycles and Medium-RingOligosilacycles (W. Ando & Y. Kabe).
Silylenes (P. Gaspar & R. West).
Indexes.
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