Enthalpies in alloys : Miedema's semi-empirical model
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書誌事項
Enthalpies in alloys : Miedema's semi-empirical model
（Materials science foundations, 1）
Trans Tech Publications, c1998
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内容説明・目次
内容説明
It is the aim of the present book to make the reader familiar with the application of a model developed by Andries Miedema which opened completely new perspectives in materials science. For example, a result that was obtained by a one-month run on a Cray 1 supercomputer turned out to be only a few kilo Joules different from the outcome by Miedema's model, obtained within a few minutes by use of a pocket calculator.
目次
- In Memoryof Andries Miedema FOREWORD PREFACE CONTENTS PART I : INTRODUCTION TO THE MODEL 1. The Macroscopic Atom Model
- Three Fundamentalquantities 2. Estimateof the Chemical Part of the Formation Enthalpy of a Dilute Random Solidsolution 3. Estimate of the Formation Enthalpy of Anintermetallic Compound 4. Volumeeffects upon Alloying 5. Solid Solubility 6. Some Thermodynamics 7. The Importance of the Structural Term 8. Surfaceenergy and Enthalpy of Atomisation PART II : APPLICATION OF THE MODEL 1. Application to the Formation and Cohesiveenthalpies of Intermetallic Compounds 2. Application to Solid Solubility 3. Formation Enthalpy of Concentrated Solidsolutions 4. Formationenthalpy of Amorphous Alloys 5. Comparison of the Formation Enthalpy of Theamorphous Alloy with the Formation Enthalpy of the Solid Solution 6. Formationenthalpy of Ternary Alloys 7. Application to Volume Effects upon Alloying 8. Applicationto the Heat of Atomisation. 9. Vacancyformation Enthalpies in Pure Metals and Alloys. 10. Anti-Site Disorder in Ordered Compounds 11. Vacancy Formation in Ordered Intermetallics 12. Anti-Site Disorder versus Triple-Defect Disorderand Schottky Defects F. 13. Crystallisation Temperature of Amorphous Alloys 14. Metal Surfaces ACKNOWLEDGEMENTS. REFERENCES. APPENDIX 1.BACKGROUND OF MIEDEMA'S MODEL 2. TABLES Tablea1. Model Parameters in the Metallicstate Table A2. Theinterfacial Enthalpy of Two Transition Metals Table A3. The Interfacial Enthalpy of Anon-Transition Element in a Transition Metal Table A4. The Interfacial Enthalpy of a Transitionmetal in a Non- Transitionelement Table A5. Bulk and Shear Moduli of Theelements Table A6. Surfaceenergies and Vacancy Formation Enthalpies of the Elements
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