Calixarenes revisited
著者
書誌事項
Calixarenes revisited
（Monographs in supramolecular chemistry）
Royal Society of Chemistry, Information Services, c1998
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注記
Includes index
内容説明・目次
内容説明
In recent years there has been growth in the field of calixarene chemsitry. This text, a sequel to the 1989 publication "Calixarenes" brings researchers up to date with current developments in this increasingly competitive area. Spanning the period 1989 to 1996, items are fully referenced and there is also an extensive bibliography. Covering in depth the synthesis, characterization and properties, as well as conformation, reactions and complex formations of these baskets, this book is the most complete treatment of the subject available for researchers employing calixarenes in their work. It builds on the framework of the first volume, and can be used by readers already familiar with the field. For those with a less detailed background, it can be used in tandem with "Calixarenes" to provide a complete picture.
目次
- From resinous tar to molecular baskets: introduction
- phenol-derived and resorcinol-derived calixarenes
- historical perspectives
- nomenclature and representation. Making the baskets - synthesis of calixarenes: one-step synthesis of calixarenes
- fragment condensation synthesis of calixarenes
- synthesis of bridged calixarenes
- synthesis of dissymmetric and asymmetric chiral calixarenes
- synthesis of calixarene-related compounds
- mechanism of calixarenes formation. Proving the baskets - the characterization and properties of calixarenes: separation and purification of calixarenes
- melting points of calixarenes
- X-ray crystallography - the ultimate proof of structure
- pKa values of calixarenes
- dipole moments of calixarenes
- spectral characteristics of calixarenes. Shaping the baskets - conformations of calixarenes: conformational representation and nomenclature
- computational studies of calixarenes conformations
- conformations of calixarenes in the solid state
- conformations of flexible calixarenes in solution
- conformationally immobile calixarenes
- factors governing conformational outcome of derivatization. Embroidering the baskets - modifying the upper and lower rims of calixarenes: modifying the lower rim of calixarenes
- modifying the upper rim of calixarenes
- oxidation of calixarenes
- reduction of calixarenes
- selective functionalization
- calixarene polymers. Filling the baskets - complex formation with calixarenes: metal ion complexes with calixarenes carrying endo OH, SH, or C=O groups
- metal cation complexes with calixarenes carrying substituents on the lower rim
- metal cation complexes with calixarenes carrying substituents on the upper rim
- anion complexes with calixarenes
- salt complexes with calixarenes
- molecular complexes with calixarenes
- supramolecular assemblies of calixarenes. Using the baskets - calixarenes in action: calixarenes as catalysts
- ion separation
- molecular separations
- calixarenes as sensors
- miscellaneous applications
- patent literature
- concluding remarks.
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