Derivatives of oxygen and sulphur
著者
書誌事項
Derivatives of oxygen and sulphur
（Soviet scientific reviews supplement series, Chemistry ; v. 4 . Heterosiloxanes / M.G. Voronkov,
Harwood Academic Pub., c1992
- タイトル別名
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Geterosiloksany
Гетеросилоксаны
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Due to the vigorous development of the chemistry of organosilicon heterocompounds in recent years, many new uses for these types of monomers and polymers have been found. This book is part of a series providing a critical examination of the available data concerning these compounds.
目次
- Part 1 Compounds containing Si-O-O group: nomenclature and classification
- methods for synthesis - inorganic silicon compounds containing Si-O-O group, reaction of R-SiX (n=1,2) with HO or NaO, reaction of R-SiX (n=1-4) with H-O-O-R, reaction of organylchlorosilanes with metallic organylhydroperoxide derivatives, preparation from triphenylhydroperoxysilane or -germane, oxidation of organosilicon compounds by oxygen and ozone, other reactions
- physical properties and structure
- chemical properties - thermolysis, photolysis, catalytic decomposition by electrophilic agents, catalytic decomposition in presence of nucleophilic reagents, acid-basic properties, protolytic reactions, redox reactions, reaction with halogen derivatives, reactions with organometallic compounds, reaction with sulphuric anhydride, reactions with retention of Si-O-O-C peroxide group, other reactions
- biological activity
- applications - initiation of processes of polymerization of unsaturated compounds, use as vulcanizing (crosslinking) agents, activation of adhesion, other uses. Part 2 Compounds containing Si-O-S group: inorganic compounds
- organic compounds - nomenclature, methods for synthesis, physical properties, chemical properties, analysis, applications.
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