Bioinorganic catalysis
著者
書誌事項
Bioinorganic catalysis
Marcel Dekker, 1999
2nd ed., rev. and expanded
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
"Provides the latest research results and suggests new topics for interdisciplinary study of metal ions, catalysis, and biochemical systems. Second Edition highlights potential applications; includes new chapters on zinc and FeS clusters; presents new X-ray analysis of metalloenzymes; and more."
目次
- Introduction to bioinorganic chemistry
- introduction to homogeneous catalysis
- relationships between enzymatic and heterogeneous catalysis
- Lewis acid properties of zinc and its development to phosphotriester detoxifying agents
- vanadiumhaloperoxidases
- molybdenum and tungsten enzymes
- catalysis by nitrogenases and synthetic analogues
- biological iron-sulfur clusters with catalytic activity
- catalysis by nickel in biological systems
- oxygen activation at Nonheme iron centres
- dioxygenactivation at Heme centres in enzymes and synthetic analogues
- biological and biomimetric catalysis of manganese redox enzymes and their inorganic models
- the two B12 cofactors - influence of the trans nitrogen ligand on homolytic and heterolyticprocesses
- formation, structure, and reactivity of copper dioxygen complexes
- multielectron transfer and catalytic mechanisms in oxidative polymerization
- metalloenzymes with a quinone cofactor
- future developments.
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