Organoselenium chemistry : a practical approach
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書誌事項
Organoselenium chemistry : a practical approach
(The practical approach in chemistry series)
Oxford University Press, c1999
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Organoselenium chemistry is proving increasingly valuable to the synthetic organic chemist. Selenium residues are easily introduced into organic molecules, they serve to effect a variety of useful transformations, and are easily removed at the end of the sequence. These processes are often characterized by high chemo- regio- and stereoselectivity. Recent enantioselective variations of selenium-mediated reactions are further extending their scope and utility. The use
of organoselenium compounds in organic conductors is another area of intense current interest. Organoselenium Chemistry - A Practical Approach is written by an international group of experts in the field.
目次
- Preface
- 1. Organoselenium chemistry: an overview
- 2. Selenoxide eliminations
- 3. Addition of Electrophilic Organoselenium Reagents to Carbon-Carbon Double Bonds
- 4. Reactions of selenium nucleophiles
- 5. Oxidations with selenium reagents
- 6. Reductions with selenium reagents
- 7. Reactions of selenium-stabilized carbanions
- 8. Reactions of selenium stabilized carbocations
- 9. Free-radical reactions and reductive deselenizations
- 10. Selenium extrusion reactions
- 11. Sigmatropic rearrangements of organoselenium compounds
- 12. Synthesis and reactions of carbonyl selenide and isoselenocyanates
- 13. Reactions of selenones
- 14. Preparation of organic conductors
- Bibliography
- Appendix
- Index
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