Organoselenium chemistry : a practical approach

著者

    • Back, Thomas G.

書誌事項

Organoselenium chemistry : a practical approach

edited by Thomas G. Back

(The practical approach in chemistry series)

Oxford University Press, c1999

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Organoselenium chemistry is proving increasingly valuable to the synthetic organic chemist. Selenium residues are easily introduced into organic molecules, they serve to effect a variety of useful transformations, and are easily removed at the end of the sequence. These processes are often characterized by high chemo- regio- and stereoselectivity. Recent enantioselective variations of selenium-mediated reactions are further extending their scope and utility. The use of organoselenium compounds in organic conductors is another area of intense current interest. Organoselenium Chemistry - A Practical Approach is written by an international group of experts in the field.

目次

  • Preface
  • 1. Organoselenium chemistry: an overview
  • 2. Selenoxide eliminations
  • 3. Addition of Electrophilic Organoselenium Reagents to Carbon-Carbon Double Bonds
  • 4. Reactions of selenium nucleophiles
  • 5. Oxidations with selenium reagents
  • 6. Reductions with selenium reagents
  • 7. Reactions of selenium-stabilized carbanions
  • 8. Reactions of selenium stabilized carbocations
  • 9. Free-radical reactions and reductive deselenizations
  • 10. Selenium extrusion reactions
  • 11. Sigmatropic rearrangements of organoselenium compounds
  • 12. Synthesis and reactions of carbonyl selenide and isoselenocyanates
  • 13. Reactions of selenones
  • 14. Preparation of organic conductors
  • Bibliography
  • Appendix
  • Index

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