CiNii Books - Hyper-structured molecules : chemistry, physics and applications

Hyper-Structured Molecules are topologically well-defined molecules in two or three dimensions, expected to show novel quantum effects in the molecular sequences. This book covers molecular designs of dendrimers, oligomers, hyperbranched polymers and/or high spin systems, molecular organizations and nanostructures, mesoscopic pattern formation, and scanning probe microscopy for characterization and molecular handling, aims at the fundamental understandings of how to design and synthesize and the future applications toward molecular electronics, photonics and spinics such as quantum effect devices. Hyper-structured Molecules III presents the frontier of novel molecules and techniques for handling them, and should be of interest to all researchers working in supramolecular chemistry or molecular electronics.

Table of Contents

Near Field Optical Technologies: From Imaging/Diagnostics to Nano-Fabrication/Atom Manipulation. Hybridization of Scanning Near-Field Optical Microscope with Scanning Tunneling Microscope, Organic Spin Clusters, Fractals and Networks with Very-High-Spin. Single Molecule Magnets, from NLO-Active Alkynylmetal Complexes to Organometallic Dendrimers. A Synthetic Approach to Rigid and Dendritic Nano-sized Ruthenium Complexes. Worm-like Dendrimers with Flexible Carbosilane Branches. Electrochemical Construction of Ordered Polyphyrin Polymers toward Nano-Molecular Spin Systems. Chromogenic Receptors as Potentially Hyper-Structured Molecules. Design and Synthesis toward Star-burst C60-Based Conducting Polyanilines. Exotic Condensed States of Matter: Discotic Mesogen and Optically Isotropic Liquid Crystals. Phototriggered Reactions of DNA and Their Applications. Optimized Second-Harmonic Generation from Alternate-Layer Langmuir-Blodgett Films of a Transparent Dye and Poly (T-butyl Methacrylate).

Volume: 2 ISBN 9789056992156

Description

Hyper-structured molecules are topologically well-defined molecules in two or three dimensions and are expected to show novel quantum effects in the molecules themselves or in molecular sequences. This book, covering the supramolecular chemistry and characterisation of hyper-structured molecules, provides an invaluable resource on the design and synthesis of topologically controlled molecules such as dendritic polymers, and on ways to handle them using techniques such as photon scanning tunnelling microscopy. The book presents a comprehensive discussion of the real application of hyper-structured molecules to organic quantum devices for molecular electronics, photonics and spinics and should be of interest to all researchers working in supramolecular chemistry and molecular electronics.

Table of Contents

Hyper-structured molecules for organic quantum devices Hiroyuki Sasabe Programming molecules to form supramolecular materials Samuel I. Stupp, Gregory N. Tew and Craig M. Whitaker The prospect of unimolecular rectification Robert M. Metzger A synthetic approach to all-carbon molecular rods with organometallic terminals Yukiko Hayaski, Masahisa Osawa and Yasuo Wakatsuki Star-branched functional polymers by living cationic polymerisation Mitsuo Sawamoto, Shokyoku Kanaoka and Toshinobu Higashimura Dendrimer porphyrins for biomimetic applications Dong-Lin Jiang, Reiko Sadamoto, Nobuyuki Tomioka and Takuzo Aida Theoretical models for molecular spinics and the possibility of spin-mediated superconductivity in hyper-structural p-d, p-d and p-R systems Kizashi Yamaguchi Approach to hyper-structured high spin molecules Tadashi Sugawara Magnetic properties of layered organic/inorganic hybrid materials Wataru Fujita, Toshihiko Yokoyama and Kunio Awaga Construction of organized porphyrin array toward photoactive molecular systems - molecular architecture using phosphorus porphyrins Hiroshi Segawa Photon-pressure exertion on mesoscopic particles in the evanescent field Satoshi Kawata Second-order nonlinear optics of chiral thin films Martti Kauranen, Thierry Verbiest, Jeffrey J. Maki, Sven Van Elshoct and Andre Persoons Index

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Hyper-structured molecules : chemistry, physics and applications

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