Metallocene-based polyolefins : preparation, properties and technology
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書誌事項
Metallocene-based polyolefins : preparation, properties and technology
（Wiley series in polymer science）
John Wiley & sons, c2000
- v. 1
- v. 2
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注記
Includes bibliographical references and index
内容説明・目次
- 巻冊次
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v. 1 ISBN 9780471999119
内容説明
The manufacture of polyolefins by metallocene catalysts represents a revolution in the polymer industry. The first, patent for a metallocene catalyst was filed in 1980 but it has been the last five years that have seen a dramatic increase in the volume of research into metallocenes and the maturing of metallocene technology. With contributions from leading experts from the US, Canada, Italy, Scandinavia, Germany and Japan, Metallocene-based Polyolefins gives comprehensive coverage of all areas of metallocene technology: catalyst structure, comonomer incorporation, polymerization mechanisms and conditions, reactor configurations, special properties, rheological and processing behaviour, comparison with conventional polyolefins and fields of application. An essential book for plastics engineers, polymer chemists, physicists, materials scientists and all those working in the plastics manufacturing and processing industries.
目次
NATURE OF METALLOCENE CATALYSTS.
Metallocene Polymerization Catalysts: Past, Present and Future (J.Ewen).
Alkylalumoxanes: Synthesis, Structure and Reactivity (A. Barron).
MAO-free Metallocene Catalysts for Ethylene (Co)Polymerization (L.Resconi, et al.).
Influence of Metallocene Structures on Molecular andSupermolecular Architectures of Polyolefins (D. Fischer, et al.).
Olefin Polymerization by Monocyclopentadienyl Compounds ofTitanium, Zirconium and Hafnium (S. Ewart M. Baird).
Molecular Architecture: A New Application Design Process MadePossible by Single-site Catalysts (A. Torres, et al.).
Generation of Cationic Active Species for Olefin Polymerizationfrom ansa-Metallocene Amide Complexes (I. Kim).
Supported Metallocene Polymerization Catalysis (J. Chien).
Supported Metallocene Catalysts for Olefin Polymerization (G.Hlatky).
Homogeneous Phosphametallocene-based Catalysts for OlefinPolymerization (M. Sone).
Nickel- and Palladium-based Catalysts for the InsertionPolymerization of Olefins (L. Johnson C. Killian).
ETHYLENE POLYMERIZATION.
Structure, Properties and Preparation of Polyolefins Produced bySingle-site Catalyst Technology (P. Chum, et al.).
New Developments in the Production of Metallocene LLDPE byHigh-pressure Polymerization (A. Akimoto A. Yano).
Metallocenes as Catalysts for the Copolymerization of Ethene withPropene and Oienes (M. Galimberti, et al.).
Copolymerization of Ethylene with Dienes Using Metallocene/MAOCatalysts (G. Jiang).
Ethylene Polymerization Using a Metallocene Catalyst Anchored onSilica with a Spacer (D.-H. Lee S. Noh).
PROPYLENE POLYMERIZATION.
Synthesis of Isotactic Polypropylene by Metallocene and RelatedCatalysts (K. Soga, et al.).
Synthesis and Properties of Metallocene Catalysts for IsotacticPolypropylene Production (W. Spaleck).
Properties of Metallocene-catalyzed Isotactic Polypropylene (W.Spaleck).
Metallocene-catalyzed Syndiotactic Polypropylene: Preparation andProperties (T. Shiomura, et al.).
Synthesis of Atactic Polypropylene Using Metallocene Catalysts (L.Resconi).
Design of Ethylene-bridged ansa-Zirconocene Dichlorides for aControlled Propene Polymerization Reaction (J. Voegele, et al.).
Index.
- 巻冊次
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v. 2 ISBN 9780471999126
内容説明
With contributions from leading international experts, thisessential book gives comprehensive coverage of all areas ofmetallocene catalysts and metallocene-based polyolefins includingdetails of the very latest developments.
The manufacture of polyolefins by metallocene catalysts representsa revolution in the polymer industry. The last five years inparticular have seen a dramatic increase in the volume of researchinto metallocenes and the maturing of metallocene technology.
The following areas are covered in this comprehensive book:catalyst structure, comonomer incorporation, polymerizationmechanisms and conditions, reactor configurations, specialproperties, comparison with conventional polyolefins, rheologicaland processing behavior and fields of application.
This is an invaluable book for plastics engineers, polymerchemists, physicists, materials scientists, and all those workingin the plastics manufacturing and processing industries.
目次
MECHANISTIC ASPECTS OF METALLOCENE CATALYSTS.
Molecular Modeling Studies on Stereospecificity andRegiospecificity of Propene Polymerizations by Metallocences (P.Corradini, et al.).
Chiropicity of Metallocene Catalysts and Propene Polymerization (G.Di Silvestro).
Stereospecific Polymerization of Chiral -Olefins (A.Zambelli).
Computational Modeling of Single-site Polymerization Catalysts (T.Woo, et al.).
CYCLOOLEFINS, DIENES AND FUNCTIONALIZED OLEFINPOLYMERIZATION.
Homo- and Copolymerization of Cycloolefins by Metallocene Catalysts(W. Kaminsky & M. Arndt-Rosenau).
Metallocene Catalysts for 1,3-Diene Polymerization (L. Porri, etal.).
New Functionalized Olefin Copolymers Synthesized by Metallocenesand Novel Organometallic Catalysts (B. Lofgren & J.Seppala).
PLASTOMERS AND ELASTOMERS.
Constrained Geometry Single-site Catalyst Technology Elastomers andPlastomers for Impact Modifications and Automotive Applications (K.Sehanobish, et al.).
Structure, Properties and Applications of Polyolefin ElastomersProduced by Constrained Geometry Catalysts (T. Ho & J.Martin).
Packaging Applications Using Enhanced Polyethylenes and PolyolefinPlastomers Produced by Contrained Geometry Single-site Catalysts(K. Koch, et al.).
Measurement, Mathematical Modeling and Control of Distribution ofMolecular Weight, Chemical Composition and Long-chain Branching ofPolyolefins Made with Metallocene Catalysts (J. Soares & A.Penlidis).
STYRENE POLYMERIZATION.
Structure, Properties and Applications of Ethylene-StyreneInterpolymers (M. Guest, et al.).
Metallocene-Based Reactive Polyolefin Copolymers Containingp-Methylstyrene (T. Chung).
COMMERCIAL METALLOCENE POLYMERIZATION METHODS.
Applications of Metallocene Catalysts to Large-scale Slurry LoopReactors (D. Fahey, et al.).
Multi-catalyst Reactor Granule Technololgy for the Production ofMetallocene Polymers (J. Haylock, et al.).
Metallocene Catalyst Technology in a Bimodal Polymerization Process(H. Knuuttila, et al.).
RHEOLOGY AND PROCESSING OF METALLOCENE-BASED POLYMERS.
Rheological Properties of Metallocene-catalyzed Polyolefins in theMelt and Solid States and Comparison with Conventional Polyolefins(J. Carella & L. Quinzani).
Rheology and Processing of Metallocene-based Polyolefins (F.Eckstein, et al.).
Melt-rheological Characteristics of Metallocene-catalyzedPolyethylenes (D. Rohlfing & J. Janzen)
Extrusion Characteristics of Metallocene-based Polyolefins (C.Cheng).
APPLICATIONS OF METALLOCENE-BASED POLYOLEFINS.
Film Applications for Metallocene-based Propylene Polymers (A.Mehta, et al.).
Medical Applications of Metallocene-catalyzed Polyolefins (R.Portnoy & J. Domine).
Constrained Geometry-catalyzed Polyolefins in Durable and Wire andCable Applications (S. Betso, et al.).
Production and Use of Metallocene-based Polyethylene in RotomoldingApplications (A. Fatnes, et al.).
Index.
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