Fluorine chemistry for organic chemists : problems and solutions
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書誌事項
Fluorine chemistry for organic chemists : problems and solutions
Oxford University Press, 2000
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注記
Includes bibliographical references (p. 113-117) and index
内容説明・目次
内容説明
This book is a synthesis of two of Hudlicky's earlier books outlining the many unpredictable properties of fluorine and its compounds that are not analogous to the properties of any other halogens and their compounds. It is divided into two separate sections, the first presenting peculiar reactions as problems to be solved. Each reaction can be analyzed in the lab without the help of the second section, however if a solution is not easily reached, the second
section provides discussion of the problems, outlining the products of the reactions and their mechanisms. Among the 105 reactions outlined are the introduction of fluorine into organic molecules, reduction and oxidation of fluorine compounds, reactions of fluorocompounds with halogens and their
derivatives, nitration, acid catalyzed reactions, organometallic syntheses, and pyrolyses. The reactions are documented in the experimental material of the earlier volumes and will be important background knowledge for anyone working in organic chemistry.
目次
Part I. Problems
1: Warmup for Inorganic Chemists
2: Introduction of Fluorine
3: Reductions
4: Oxidations
5: Preparation of Halogen Derivatives
6: Nitration
7: Reactions of Sulfur Trioxide
8: Acid-Catalyzed Additions and Substitutions
9: Hydrolyses
10: Alkylations
11: Arylations
12: Acylations
13: Aldol-Type Condensations
14: Organometallic Syntheses
15: Additions
16: Eliminations
17: Rearrangements
Part II. Solutions
References
Author Index
Subject Index
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