Polyoxometalate chemistry form topology via self-assembly to applications
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書誌事項
Polyoxometalate chemistry form topology via self-assembly to applications
Kluwer Academic Publishers, c2001
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
This book provides an authoritative up-to-date summary of the chemistry and applications of polyoxometalates with emphasis on new synthetic strategies directed towards functionalized organic derivatives, self-assembly of mesoscopic composite polyoxoanions, generation of framework materials and thin oxide films, extended optical, magnetic, and electrical properties, applications in homogeneous and nanocluster-based catalysts, photocatalytic water decontamination, ribosomal crystallography, and topological aspects of large symmetrical structures.
目次
- Introduction to Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications
- M.T. Pope, A. Muller. Synthetic Strategies. 1. Rational Approaches to Polyoxometalate Synthesis
- R.J. Errington. 2. Functionalization of Polyoxometalates: Achievements and Perspectives
- A. Proust, R. Villaneau. 3. From the First Sulfurated Keggin Anion to a New Class of Compounds Based on the [M2O2S2 2+ Building Block M-Mo,W
- E. Cadot, et al. 4. Organometallic Oxometal Clusters
- A. Proust, et al. Structures: Molecular and Electronic. 5. Spherical (Icosahedral) Objects in Nature and Deliberately Constructable Molecular Keplerates: Structural and Topological Aspects
- O. Delgado, et al. 6. Synthesis and Crystal Structure Studies of Novel Selenium- and Tellurium-Substituted Lacunary Polyoxometalates
- B. Krebs, et al. 7. Vibrational Spectroscopy of Heteropoly Acids
- H. Ratajczak, et al. 8. Bond-Stretch Isomerism in Polyoxometalates?
- M.-M. Rohmer, et al. 9. Quantum-Chemical Studies of Electron Transfer in Transition-Metal Substituted Polyoxometalates
- S.A. Borshch, H. Duclusaud. Solution Equilibria and Dynamics. 10. Aqueous Peroxoisopolyoxometalates
- O.W. Howarth, et al. 11. Molybdate Speciation in Systems Related to the Bleaching of Kraft Pulp
- F. Taube, et al. 12. NMR Studies of Various Ligands Coordinated to Paramagnetic Polyoxometalates
- B.A. Kim, H. So. From Discrete Clusters to Networks and Materials. 13. Molecular Aspect of EnergyTransfer from Tb3+ to Eu3+ in the Polyoxometalate Lattices: An Approach for Molecular Design of Rare-Earth Metal-Oxide Phosphors
- T. Yamase. 14. Conducting and Magnetic Organic / Inorganic Molecular Materials Based on Polyoxometalates
- L. Ouahab, et al. 15. Molecular Materials From Polyoxometalates
- J.J. Borras-Almenar, et al. 16. Framework Materials Composed of Transition Metal Oxide Clusters
- M.I. Khan. 17. Perspectives in the Solid State Coordination Chemistry of the Molybdenum Oxides
- P.J. Hagrman, et al. 18. Polyoxometalate Clusters in a Supramolecular Self-Organized Environment: Steps Towards Functional Nanodevices and Thin Film Applications
- D.G. Kurth, D. Volkmer. 19. Polyoxometalate Chemistry: A Source for Unusual Spin Topologies
- D. Gatteschi, et al. 20. Heteropolyanions: Molecular Building Blocks for Ultrathin Oxide Films
- J.D. Powell, et al. Applications: Catalysis, Biological Systems, Environmental Studies. 21. Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-substituted Silicotungstates
- N. Mizuno. 22. Aerobic Oxidations Catalyzed by Polyoxometalates
- A.M. Khenkin, et al. 23. Polyoxoanions in Catalysis: From Record Catalytic Lifetime Nanocluster Catalysis to Record Catalytic Lifetime Catechol Dioxygenase Catalysis
- R.G. Finke. 24. Ribosomal Crystallography and Heteropolytungstates
- D. Janell, et al. 25. Photocatalytic Decontamination by Polyoxometalates
- A. Hiskia, et al. Index.
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