Applications of synthetic resin latices
著者
書誌事項
Applications of synthetic resin latices
Wiley, c2001
- v. 1
- v. 2
- v. 3
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v. 1578-4-55//1030200105829,
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注記
Includes bibliographical references and indexes
収録内容
- v. 1. Fundamental chemistry of latices and applications of adhesives
- v. 2. Latices in surface castings : emulsion paints
- v. 3. Latices in diverse applications
内容説明・目次
- 巻冊次
-
v. 1 ISBN 9780471952688
内容説明
This book covers the fundamental chemistry of latices and their applications in adhesives. These water-based latices are playing a far greater role in many applications and match the growing concern over environmental safety. This book is available separately or as part of a 3-volume set and offers an insight into the advances and developments in this field.
* Introduces the principles and practice of emulsion polymerisation and of the resulting latices and their properties
* Includes alkali-solubility, in relation to the requirements of specific applications, including pigmented systems and technical latices
* Contains a comprehensive account of the formulation of latex-based adhesives for the bonding of many different substances
As a comprehensive account of the science of polymer latices, these volumes are an invaluable resource for research workers and end-users in academia and industry working on water-based paints, adhesives, emulsions, dispersions and coatings.
目次
- Preface. Applications--A Note on References. Patent Viability. Introduction. FUNDAMENTALS OF POLYMER CHEMISTRY. The Concept of a Polymer. Historical Introduction. Definitions. Addition Polymerisation. Free radical polymerisation. Copolymerisation. Chain Branching
- Block and Graft Copolymers. Chain Branching. Graft Copolymers. Polymer Structure and Properties. Polymer structure. Molecular weight effects. Transition points. Technology of Polymerisation. Bulk polymerisation. Solution polymerisation. Suspension polymerisation. The Principal Monomers and Their Polymer. Hydrocarbons. Vinyl esters. Clorinated monomers. Acrylics. Polymerisable acids and anhydrides. Self-emulsifying monomers. Esters for copolymerisation. Monomers with several double bonds. Allyl derivatives. Vinyl ethers. Miscellaneous monomers containing nitrogen. Toxicity and handling. Physical Properties of Monomers. Appendix. References. EMULSIONS AND COLLOIDS. Introduction to Colloid Chemistry. Historical. Emulsions. Surfactants and Stabilisers. A Survey of Technical Surfactants. Anionic types-fatty acids and allied salts. Sulfates and sulfonates. Hydrotropes. Phosphates. Fluorochemical emulsifiers. Non-ionic types. Biodegradable emulsifiers. Cationic types. Amphoteric emulsifiers. Polymerisable agents. Dispersing agents. Solid dispersants. Colloids and High Molecular Weight Stabilisers. Starch and dextrin. Cellulose ethers. Other semi-synthetic colloids. Polyvinyl alcohol. Polyelectrolytes. Other synthetic water-soluble polymers. Associative thickeners. References. Supplementary references for Section 3.9. EMULSION POLYMERISATION. General Principles. Chemistry and fundamentals. Technology, Laboratory and Large Scale. Monomers. Pilot plants and large-scale reactors. Special techniques
- continuous processes. Varied polymerisation techniques. Vinyl Acetate and Copolymer Latices. Historical development of latices. Polyvinyl acetate and related coploymers. Copolymers of vinyl acetate. Alkali-soluble polymers. Equivalence of 'external' and 'internal' plasticisation. Acrylic Latices. Typical acrylic formulations. Developments in polymerisation of acrylics. Styrene Latices. Processes-general. Diene Polymers and Copolymers. Introduction. Dienes: non-rubber applications. Carboxylated latex formulations. Vinyl Halides. Vinyl chloride polymers and copolymers. Vinylidene chloride polymers and copolymers. Monomers containing bromine. Vinyl compounds containing fluorine. Emulsion Polymerisation-Theoretical Considerations. Types of mechanism. Theories of Harkins and Smith and Ewart. Theory of Medvedev. Theoretical developments-Fitch and Ugelstadt. Copolymerisation-theoretical. Specificity of surfactants and stabilisers. Latex particle stablization. Further quantitative investigations. 1 Styrene. Emulsion polymerisation, acrylic and methacrylic esters. Emulsion polymerisation of vinyl acetate. Styrene copolymers (except with dienes). Butadiene copolymers. Copolymerisation including a water-soluble monomer. Emulsion Polymerisation in Supercritical Carbon Dioxide. Inverse Emulsions. Interpenetrating Networks (IPN). Conclusions. References. LATEX PROPERTIES RELATIVE TO APPLICATIONS. Introduction. Various Properties and Descriptions. Emulsion particles and resultant properties. Particle characterization. Core-shell copolymers-surface and buried groups. Adsorption of surfactants on latex particles. Emulsion viscosity. Freeze-Thaw and Tropical Stability. Freeze-thaw stability-general principles. Freeze-thaw stability-technical methods of control. Freeze-thaw stability-tests. Tropical stability. Emulsion Films. Film formation. Theoretical developments. Minimum film-forming temperature. Specific studies-film formation. Summary. Addition of Plasticisers and Coalescing Solvents. Introduction. The mechanism of platicisation in emulsion. Plasticisation of principle polymers. Transient plasticisers (coalescing solvents). Pigementation. Introduction. Pigmentary power. Some common pigments and extenders. Pigmentation of latices. General properties of pigmented systems. Critical pigment volume concentration. Pigment encapsulation. Organic Extenders. References. CROSSLINKING AND CURING. Introduction. Problems of crosslinking in latices. A survey of crosslinking. Estimation of Crosslinking. Cure studies. Cure tests. Multiple Double Bonds. Polymers including divinylbenzene and allied monomers. Polymers derived from acrylic and allied esters-multiple double bonds. Allyl polymers-multiple double bonds. Diene polymers. Other vinyl-type polymers with residual unsaturation. The Carboxyl Function in Polymers. Introduction. Combinations with hydroxyl and epoxide groups. Metal oxides. The Hydroxyl Function. Reactions with aldehydes. Dioxalane derivatives. The Epoxide Function. Internal epoxide groups in unsaturated monomer. External epoxide compounds. Di-Isocyanates and Polyurethanes In Vinyl-Type Cures. Polymers Containing (Meth)Acrylamide. Chemistry of the reactions. Simple derivatives of acrylamide. Diacetoneacrylamide (DAAM). Methylene bis acrylamide (MBAM). The aminimides. Acrylamidoglycollates. Other amide derivatives with unsaturation. Cure with aminoplasts. Polymers Containing Halogens. Radiation Curing. Ultraviolet curing. Cure by electron beam (EB). Incorporation of Siloxanes. Cure of Eva and Saturated Polymers. Other Crosslinking Systems. Acid and alkali induced crosslinking. Crosslinking via beta-ketonic acid esters. Crosslinking with reactive nitrogen compounds. Intra- and inter-molecular reactions. Unspecified. References. TECHNICAL POLYMER LATICES. Introduction. Polyvinyl Acetate and Related Polymers. Polyvinyl acetate. Copolymers of dinyl acetate. Typical commercial products. Acrylic Polymers and Copolymers. Properties of acrylic polymers. Properties of acrylic resin films. Vinyl Halide Polymers. Polyvinyl chloride. Polymers and copolymers of vinylidene chloride. Fluorocarbon latices. Styrene Polymers and Copolymers. Polystyrene. Styrene-butaiene copolymers. Polymers Based on Aliphatic Hydrocarbons. Vinylpyrrolidone Copolymersd. The Testing of Latices. Total solids content. Monomer content. Specific gravity. pH stability. Freeze-thaw stability. Emulsion viscosity. Particle size. Soap titration
- surface tension measurements. Settling and sedimentation. Mechanical stability. Minimum film temperature (MFT). Relative molecular weight (viscosity). General film measurements. Determination of charge. UNSATURATED POLYMERS AND NON-VINYL EMULSIONS. Introduction. Alkyds and Polyesters. Polyesters. Alkyds and allied products. Aminoplasts. Polyamide Emulsions. Epoxide Resins and Blends. Initial condensation in emulsion. Amine salt emulsification. Non-ionic emulsifiers. Cycloaliphatic epoxides. Water-in-oil emulsions. Epoxides containing halogens. Epoxide-polyamide emulsions. Epoxide emulsions-miscellaneous blends and reactions. Applications. Phenoplasts. Silicones. Elementary chemistry. Some methods of emulsification. Textile and paper applications of silicone oragnopolysiloxane latices. Silicone latices in surface coating and building. Miscellaneous applications. Polyurethanes. Chemistry of isocyanate adducts. Polyurethane latex. Applications of polyurethane latices. References. POLYMER LATICES IN THE FORMULATION OF ADHESIVES. Introduction. Terminology of adhesives. Survey of Theories of Adhesion. Basic theory. The function of adhesives: latex adhesives. Latex-Based Adhesives: Some Practical Aspects. Introduction. Functions of adhesives. Practical requirements of adhesives. Specific Adhesive Types. Polyvinyl acetate homopolymer-based adhesives. Polyvinyl acetate copolymer-based adhesives. Polyvinyl propionate latices in adhesives. Acrylic copolymer latices. Vinylidene chloride and other halogenated polymer latices in adhesive. Butadiene coploymer latices. Other latex types. Latex-Based Adhesives with Specific Functions. Pressure-sensitive adhesives. Removable pressure-sensitive adhesives. Contact adhesives. Heat-seal adhesives. Delayed tack adhesives. Remoistenable adhesives. Quick-tack and contact-grab adhesives. Redispersible components for pressure-sensitive adhesives. Adhesive for Specific Applications. Wood adhesives. Latex-based adhesives for paper bonding. Adhesives for packaging. Miscellaneous latex-based adhesives. Rubber-to-Fabric Adhesives. Introduction. Vinylpyriding copolymer adhesives. Dip additives and composition. Other rubber adhesive systems. Modifications of resorcinol-formaldehyde resins. Latex modifications. Test Methods for Adhesives. Appendix: Some Technical Products for Water-Based Adhesives. Glossary of Terms Relating to Adhesives. References. Index.
- 巻冊次
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v. 2 ISBN 9780471954613
内容説明
This volume discusses latices in surface coatings in regards to emulsion paints. These water-based latices are playing a far greater role in many applications and match the growing concern over environmental safety. This book is available separately or as part of a 3-volume set and offers an insight into the advances and developments in this field.
* Describes the principles of the formulation, manufacture and application properties of water-based 'emulsion' paints and related surface coatings
* Includes inter alia gloss and anti-corrosion paints and electrocoating
As a comprehensive account of the science of polymer latices, these volumes are an invaluable resource for research workers and end-users in academia and industry working on water-based paints, adhesives, emulsions, dispersions and coatings.
目次
- Preface. A Note on References. Patent Validity. Introduction. SURFACE COATINGS, DECORATIVE, FUNDAMENTALS AND RAW MATERIALS. Historical Introduction. Fundamental Formulation and Requirements. The principal constituents. General emulsion requirements. Plasticisation, including transient plasticisers. Corrosion resistance [storage]. Vinyl Acetate Polymers and Copolymers. Homopolymers
- formulation. Paint formulation-general. Plasticiser variations. Vinyl acetate copolymer latices. Formulation of copolymer latices and paints. Chemically resistant copolymer latices. Vinyl acetate-olefin copolymers. Miscellaneous and crosslinking additives. Prepigmented latices. Acrylic Latices as Paint Media. General properties. Formulation modificcations. Acrylics with reactive groups. Technical latices. Manufacturing techniques for acrylic latex paints. Comparisons of vinyl ester/acrylic latices for latex paints. Hydrocarbon Polymer Emulsion Paints. Styrene latices. Styrene-butadiene copolymers. Vinyl Halide Polymers. Vinyl chloride-vinyl ester copolymers. Vinyl chloride-ethylene copolymers. Polymers including fluorine. Miscellaneous and Crosslinked Polymers. 'Core-shell' type copolymers in emulsion. Emulsion Comparisons. Photochemical degradation. Pigments. Titanium dioxide. Zinc oxide. Lithopone and antimony oxide. Metallic aluminium pigments. The Principal Extenders. Formulation with extenders. Coloured Pigments. Universal Tinters. Dispersible pigment powders. Organic Extenders. EMULSION PAINTS-FORMULATION. Aspects of Emulsion Paint Rheology. Effects of surfactants. Dispersion and dispersing agents. General colloid effects. Viscosity. Thixotropy and related phenomena. Surfactant transfer. Foam control agents. Adhesion. Temperature Stability. Freeze-thaw stability. HIgh-temperature (tropical) stability. Film Formation. Film drying and pH effects. Water resistance of paint films. Efflorescence: lime staining. Specific claims to film formation. Microbiological Problems, Other Organic Growths and Remedies. Introduction. Microbiocides-general. Microbiocides-metal componds. Studies on fungicides and fungistats. Bactericides and bacteriostats. Some miscellaneous microbiocidal agents. Algae. Polymers with microbiocidal properties. Miscellaneous test. General papers. Undercoats, Primer-Sealers and Recoating Old Oil/Alkyd Paints. Vinyl acetate polymers. Acrylic copolymers. Paints including drying oil fatty acid derivatives. Gloss Emulsion Paints. Introduction and definitions. Rheology-flow and levelling. Pigments-flow and levelling. Film properties. Paint media-vinyl acetate polymer and copolymer latices. Acrylic copolymer latices. Vinylidene chloride copolymer latices. Core-shell and graft copolymers. Pigments-specific. Emulsion stabilisers and pigment dispersants. Additives for flow improvement. Mulitcoats. Thixotropy. Semi-gloss paints. Ambient crosslinking. Prepigmented latices. Polyurethane and silicone latices. General papers of interest. Emulsion Paints for Exterior Use. General requirements. Pigments and Extenders. Inclusion of associative thickeners. Exterior surfaces (except wood). Wood coatings. General. Specific problems and cures. Tests on wood coatings. Vinyl and acrylic formulations. Adhesion improvement. Emulsion Paints for Interior Use. Fire-Retardant Paints. Introduction-problems and general methods for fire retardancy. Studies and tests for fire retardance. Intumescent coatings. Emulsion Paints as Metal Coatings. The nature of the problem. Anticorrosive pigments. Miscellaneous metals and metal salts. Minerals and extenders. Prevention of migration of soluble iron salts-borates. Basic nitrogen compounds and amides. Miscellaneous additives. Specific emulsion types. Acrylic ester and acrylic ester-styrene latices. Coatings for automobiles. Unclassified. Vinyl acetate copolymers. Copolymers including ethylene. Paints containing a vinyl halide. Paints containing a silicone derivative. Strippable corrosion-resistant paint. An application trial. Incorporation of rust in films. Latices including cement. Coatings on aluminium, zinc and copper. Coatings on Cement and Building Boards. Cement and concrete coatings. Coatings for slate. Miscellaneous. Special Procedures. Coatings with gas and moisture barrier properties. Reconstitutable emulsions. Prepigmented latices. Removable coatings. Gelled water-based coatings. Paints derived from alkyds and miscellaneous macromolecules. Special Additions. Zirconyl and zinc compounds. Addition of barium compounds
- effervescent pigments. Special Effects. Various patterned effects. Multicolour paints. Conductive paints. Artists' Paints. Conclusion. Appendix: The Testing of Emulsion Paints. Viscosity. Film application: fineness of grind. Scrub and wash resistance of paint films. Gloss
- opacity. Differential thermal analysis (DTA). Adhesion tests. Some ASTM standard test methods. References. INDUSTRIAL FISHING. Introduction: Definitions. Water-based industrial finishes. Pre-treatment: acid etching of metal surfaces by wash primers. Combinations of Carboxyl and Aminoplast. Typical examples. Combinations of carboxyl, hydroxyl and aminoplast. Combinations of Carboxyl with Other Reactive Groups. Wire enamels. The Hydoxyl and Epoxide Groups. The hydoxyl group. Epoxide reactions. Hydroxyl reactions with di-isocyanates. Finishes Containing Acrylamide and its Derivatives. Introduction. Finishes containing acrylamide and N-methylolacrylamide. Butoxy- and isobutoxymethacrylamide. Inclusion of epoxide groups. Other derivatives of acrylamide. Styrene-butadiene latices including acrylamide and derivatives. Finishes including vinyl chloride. Finishes including acrylamide derivatives and aminoplasts/phenoplasts. Theoretical investigations. Reviews. Finishes Including Dienes. Pre-application grain-boundary etch. Metal compound cure. Addition of acids. Grafted polymers. Blends with phenoplasts or aminoplasts. Miscellaneous additions. Self-Curing Coatings. Self-cure including silicates. Acrylic esters with unsaturated emulsifiers. Electroless (Auto) Deposition. Miscellaneous. Electrodeposition. Electrochemical principles and definitions. Fundamental studies and reviews. The electrocoating bath. The deposits. Technological improvements. Patented processes. Cathodic depostion. References. Index.
- 巻冊次
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v. 3 ISBN 9780471954620
内容説明
This volume discusses latices in surface coatings in regards to diverse applications. These water-based latices are playing a far greater role in many applications and match the growing concern over environmental safety. This book is available separately or as part of a 3-volume set and offers an insight into the advances and developments in this field.
* Covers the principles and practice of the use of latex-based systems in building and construction products, paper coating, textile treatment, polishes and many other specialised applications
As a comprehensive account of the science of polymer latices, these volumes are an invaluable resource for research workers and end-users in academia and industry working on water-based paints, adhesives, emulsions, dispersions and coatings.
目次
Preface.
A Note on References.
Patent Validity.
Introduction.
Applications of Synthetic Resin Latices in the Construction and Building Industries--Bonding and Sealants.
Introduction.
Adhesives and Sealants.
Plasters and Hydraulic Binding Agents.
Cement Additives.
Formulations for Specific Applications.
Latex-based Additivies for Cement Formulations.
Cement-Free Compositions.
Decorative Facings and Wall Coatings.
Applications of Latices in the Paper Industry.
General Introduction.
Beater Addition.
Impregnation of Paper.
Paper and Paperboard Coatings.
Wallpaper Coatings.
Special Coatings and Effects.
Methods of Paper Testing.
Latices in Leather Finishing.
General.
Finishing.
Leather as a Substrate.
Leather Finishing Binders.
Some Specific Formulations.
Polymerisation in situ in Skins.
Treatment with Non-vinyl Latex Dispersions.
Binding of Leather Scrap with Latices.
Test Methods.
Applications of Polymer Latices in Manufacture and finishing of Textiles.
Introduction.
Warp Sizing.
Sizing with Vinyl Latices.
Finishing with Crosslinking Resins.
Cationic Finishes.
Treatment of Specific Fibres and Fabrics.
Finishes for Specific Objectives.
Fabric Laminating and Flocking.
Latices in Non-Woven Fabric Manufacture.
Carpet and Upholstery Applications.
Pigment Dyeing and Printing.
Coated and Impregnated Fabrics.
Direct Fibre Spinning from Emulsions.
Applications of Synthetic Resin Latices in Polishes.
Introduction.
Emulsion Polish Ingredients.
Waxes, Natural and Synthetic.
Alkali-Soluble Resins.
Plasticisers and Levelling Agents.
Minor Additives.
Formulation of Polishes and Sealants.
Polymer Latices with Metal-Based Crosslinking Agents.
Acid-Removable Polishes.
Miscellaneous Applications of Polymer Latices.
Introduction.
Applications as a Binder.
Applications Related to Foods.
Glass Fibre Treatment.
Vibration Damping and Sound Deadening.
Photographic and Copying Systems.
Coatings for Synthetic Films and Sheets.
Other Miscellaneous Applications of Latexes.
Non-film-Forming Latices.
Index.
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