Cycloaddition reactions in organic synthesis
著者
書誌事項
Cycloaddition reactions in organic synthesis
Wiley-VCH, c2002
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Cycloaddition reactions are among the most important tools for synthesis in organic chemistry, since these reactions are vital to the modern synthesis of natural products and biologically active substances. Metal catalysis plays an increasingly important role in these reactions, often allowing several stereocenters to be selectively created and integrated in the target molecules. Kobayashi and Jorgensen's handbook provides numerous examples of metal-catalyzed reactions, including [2+1], [3+2] and [4+2] cycloadditions. Important reactions such as carbo- and hetero-Diels-Alder, carbocyclic, cyclopropanation and 1,3-dipolar cycloaddition reactions are discussed. A large number of experimental procedures gives a concrete idea of the use of metal-catalyzed cycloaddition reactions in modern synthesis. The book is aimed at chemists in industry or academia, who want to effectively use cycloadditions in their work.
目次
List of Contributors. Introduction. References. Catalytic Asymmetric Diels--Alder Reactions (Yuyiro Hayashi). Recent Advances in Palladium--catalyzed Cycloadditions Involving Trimethylenemethane and its Analogs (Dominic M.T. Chan). Enantioselective [2+1] Cycloaddition: Cyclopropanation with Zinc Carbenoids (Scott E. Denmark and Gregory Beutner). Catalytic Enantioselective Cycloaddition Reactions of Carbonyl Compounds (Karl Anker Jorgensen). Catalytic Enantioselective Aza Diels--Alder Reactions (Shu Kobayashi). Ssymmetric Metal--catalyzed 1,3--Dipolar Cycloaddition eactions (Kurt Vesterager Gothelf). Aqua Complex Lewis Acid Catalysts for Asymmetric 3+2 Cycloaddition Reactions (Shuji Kanemasa). Theoretical Calculations of Metal--catalyzed Cycloaddition Reactions (Karl Anker Jorgensen). Index.
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