Nonadiabatic transition : concepts, basic theories and applications

Bibliographic Information

Nonadiabatic transition : concepts, basic theories and applications

by Hiroki Nakamura

World Scientific, c2002

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Note

Includes bibliographical references (p. 361-370) and index

Description and Table of Contents

Description

Nonadiabatic transition is a highly multidisciplinary concept and phenomenon, constituting a fundamental mechanism of state and phase changes in various dynamical processes of physics, chemistry and biology, such as molecular dynamics, energy relaxation, chemical reaction, and electron and proton transfer. Control of molecular processes by laser fields is also an example of time-dependent nonadiabatic transition. Thus, nonadiabatic transition represents one of the very basic mechanisms of the mutability of the world. This book has been written because the complete analytical solutions to the basic problem have recently been formulated by the author.

Table of Contents

  • Introduction - what is "nonadiabatic transition"?
  • multidisciplinarity
  • historical survey of theoretical studies
  • background mathematics
  • basic two-state theory for time-independent processes
  • basic two-state theory for time-dependent processes
  • two-state problems
  • effects of dissipation and fluctuation
  • multi-channel problems
  • multi-dimensional problems
  • complete reflection and bound states in the continuum
  • new mechanism of molecular switching
  • control of nonadiabatic processes by an external field
  • conclusions - future perspectives.

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