Dipole moments, quadrupole coupling contents, hindered rotation and magnetic interaction constants of diamagnetic molecules

書誌事項

Dipole moments, quadrupole coupling contents, hindered rotation and magnetic interaction constants of diamagnetic molecules

editor: W. Hüttner ; authors: J. Demaison, H. Hübner, W. Hüttner, J. Vogt, G. Wlodarczak

(Landolt-Börnstein Zahlenwerte und Funktionen aus Naturwissenschaften und Technik, Neue Serie / Gesamtherausgabe, K.-H. Hellwege, New Series, Group 2 . Molecules and radicals ; v. 24 . Molecular constants : Mostly from microwave, molecular beam, and sub-doppler laser spectroscopy ; subv. C)

Springer, c2002

タイトル別名

Landolt-Börnstein : Numerical data and functional relationships in science and technology, new series

Rotational and related constants of diamagnetic diatomic, linear, and symmetric rotors

Molecular constants : diatomic, linear and symmetric rotors

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注記

"Group II : Molecules and Radicals, volume 24, supplement to Vol.II/4,II/6,II/14,and II/19" -- t.p.

Includes bibliographical references

内容説明・目次

内容説明

Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. In addition, gas phase data have been included derived from methods related to microwave spectroscopy by employing a coherent radiation source. These are molecular beam techniques, radio frequency spectroscopy, electron resonance spectroscopy, laser spectroscopy, double resonance and saturation techniques. Some other methods are considered if the accuracy of the derived molecular parameters is comparable to that of microwave spectroscopy owing to a good statistics in the analysis of data, and no microwave data are available. Examples would be Fourier infrared spectroscopy or laser induced fluorescence.

目次

The present subvolume II/24 C contains the parameters of diamagnetic molecules suited for the prediction of line splittings of rotational transitions caused by other than rotational-vibrational interactions. This includes external-field effects causing the removal of M-degeneracies. In detail, in II/24 C are listed the electric dipole moments (sometimes also static polarizability anisotropies in case the Stark effect was observed up to very high field strengths), the quadrupole coupling constants, the parameters drawn from the analysis of hindered rotation of methyl groups or other internal motions (potential barriers, moments of inertia of atomic groups), and magnetic interaction constants. The latter are meant to include zero-field parameters such as spin-rotation and direct nuclear spin-nuclear spin interaction strengths as well as Zeeman effect parameters.

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詳細情報

  • NII書誌ID(NCID)
    BA58656941
  • ISBN
    • 3540410376
  • 出版国コード
    gw
  • タイトル言語コード
    eng
  • 本文言語コード
    eng
  • 出版地
    Berlin
  • ページ数/冊数
    ix, 296 p.
  • 大きさ
    28 cm
  • 付属資料
    1 CD-ROM
  • 親書誌ID
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