Ionic liquids in synthesis
著者
書誌事項
Ionic liquids in synthesis
Wiley-VCH, c2003
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
The demand for increasingly clean and efficient chemical syntheses is becoming more urgent from both an economic and an environmental standpoint. The development of ionic liquids that are fluid at room temperature is a major advance in green chemistry. These new green "designer-solvents" are less toxic and therefore more environmnetally friendly. This book brings together the latest developments in this fascinating field: It guides readers through both theory and application of this new approach The editors are pioneers on this cutting-edge field of research It is relevant to industry as these solvents prove to be cost-effective Ionic Liquids in Synthesis serves as both an introduction to the field and as a source of advanced material for experts.
目次
- Preface
- Contributors
- INTRODUCTION
- SYNTHESIS AND PURIFICATION OF IONIC LIQUIDS
- Synthesis of Ionic Liquids
- Quality Aspects and Other Questions Related to Commercial Ionic Liquid Production
- Synthesis of Task-specific Ionic Liquids
- PHYSICOCHEMICAL PROPERTIES OF IONIC LIQUIDS
- Melting Points and Phase Diagrams
- Viscosity and Density of Ionic Liquids
- Solubility and Solvation in Ionic Liquids
- Gas Solubilities in Ionic Liquids
- Polarity
- Electrochemical Properties of Ionic Liquids
- MOLECULAR STRUCTURE AND DYNAMICS
- Order in the Liquid State and Structure
- Quantum Mechanical Methods for Structure Elucidation
- Molecular Dynamics Simulation Studies
- Translational Diffusion
- Molecular Reorientational Dynamics
- ORGANIC SYNTHESIS
- Stoichiometric Organic Reactions and Acid-Catalyzed Reactions in Ionic Liquids
- Transition Metal Catalysis in Ionic Liquids
- Ionic Liquids in Multiphasic Reactions
- Multiphasic Catalysis with Ionic Liquids in Combination with Compressed CO 2
- INORGANIC SYNTHESIS
- Directed Inorganic and Organometallic Synthesis
- Making of Inorganic Materials by Electrochemical Methods
- POLYMER SYNTHESIS IN IONIC LIQUIDS
- Introduction
- Acid-catalyzed Cationic Polymerization and Oligomerization
- Free Radical Polymerization
- Transition Metal-catalyzed Polymerization
- Preparation of Conductive Polymers
- Conclusions
- BIOCATALYTIC REACTIONS IN IONIC LIQUIDS
- Introduction
- Biocatalytic Reactions and their Special Needs
- Examples of Biocatalytic Reactions in Ionic Liquids
- Conclusions and Outlook
- OUTLOOK
- INDEX
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