Advances in catalytic activation of dioxygen by metal complexes
著者
書誌事項
Advances in catalytic activation of dioxygen by metal complexes
(Catalysis by metal complexes, v. 26)
Kluwer Academic, c2003
大学図書館所蔵 全9件
  青森
  岩手
  宮城
  秋田
  山形
  福島
  茨城
  栃木
  群馬
  埼玉
  千葉
  東京
  神奈川
  新潟
  富山
  石川
  福井
  山梨
  長野
  岐阜
  静岡
  愛知
  三重
  滋賀
  京都
  大阪
  兵庫
  奈良
  和歌山
  鳥取
  島根
  岡山
  広島
  山口
  徳島
  香川
  愛媛
  高知
  福岡
  佐賀
  長崎
  熊本
  大分
  宮崎
  鹿児島
  沖縄
  韓国
  中国
  タイ
  イギリス
  ドイツ
  スイス
  フランス
  ベルギー
  オランダ
  スウェーデン
  ノルウェー
  アメリカ
注記
Includes bibliographical references and index
内容説明・目次
内容説明
The subject of dioxygen activation and homogeneous catalytic oxidation by metal complexes has been in the focus of attention over the last 20 years. The widespread interest is illustrated by its recurring presence among the sessions and subject areas of important international conferences on various aspects of bioinorganic and coordination chemistry as well as catalysis. The most prominent examples are ICCC, ICBIC, EUROBIC, ISHC, and of course the ADHOC series of meetings focusing on the subject itself. Similarly, the number of original and review papers devoted to various aspects of dioxygen activation are on the rise. This trend is due obviously to the relevance of catalytic oxidation to biological processes such as dioxygen transport, and the action of oxygenase and oxidase enzymes related to metabolism. The structural and functional modeling of metalloenzymes, particularly of those containing iron and copper, by means of low-molecular complexes of iron, copper, ruthenium, cobalt, manganese, etc., have provided a wealth of indirect information helping to understand how the active centers of metalloenzymes may operate. The knowledge gained from the study of metalloenzyme models is also applicable in the design of transition metal complexes as catalytsts for specific reactions. This approach has come to be known as biomimetic or bioinspired catalysis and continues to be a fruitful and expanding area of research.
目次
- 1: Catalytic oxidations using ruthenium porphyrins
- M.B. Ezhova, B.R. James. 1. Introduction: oxygenase and oxidase activity. 2. Reactions of ruthenium porphyrin complexes with O2 and other oxidants. 3. Oxidation of organic substrates. 4. Conclusions. 5. Abbreviations. 6. References. 2: Copper-dioxygen complexes and their roles in biomimetic oxidation reactions
- C. Xin Zhang, Hong-Chang Liang, K.J. Humphreys, K.D. Karlin. 1. Introduction. 2. Copper-dioxygen adducts. 3. Copper oxygenase chemistry. 4. Copper oxidase models: catalytic alcohol oxidation. 5. Copper-phenanthroline DNA oxidation. 6. References. 3: Catalytic oxidations of alcohols. R.A. Sheldon, I.W.C.E. Arends. 1. Introduction. 2. Mechanisms. 3. Ruthenium-catalysed oxidations with O2. 4. Palladium- catalysed oxidations with O2. 5. Copper- catalysed oxidations with O2. 6. Other metals as catalysts for oxidation with O2. 7. Catalytic oxidation of alcohols with hydrogen peroxide and alkyl hydroperoxides. 8. Concluding remarks. 9. references. 4: Functional model oxygenations by nonheme iron complexes. T. Funabiki. 1. Introduction. 2. heme and nonheme oxygenases. 3. Functional model studies on nonheme iron. 4. Functional model systems for nonheme iron monooxygenases. 5. from functional model to catalysis. 6. References. 5: Catalysis for selective aerobic oxidation under ambient conditions. E. Boring, Y.V. Geletti, C.L. Hill. 1. Introduction. 2. Discovery of Au(III)Cl2NO3(thioether)/O2 catalytic oxidation system. 3. Stoichiometric Au(III) reduction by thioethers. 4. In situ catalyst preparation. 5. Reaction stoichiometry. 6. Empirical reaction rate law. 7. Rate limiting step. 8. proposed reaction mechanism. 9. Mechanisms ruled out. 10. Origin of oxygen in sulfoxide product: role of H2O2 in sulfoxidation. 11. Reoxidation of Au(I) by dioxygen. Catalyst preparation from Au(I) complex. 12. Effect of ligands on reactivity. 13. Product inhibition (DMSO) effect. 14. Co-catalysis by transition metal ions. 15. Solvent effects. 16. Heterogeneous systems. 17. Effect of amino acids. 18. Oxidation of thioethers other than CEEs. 19. Experimental details. 20. Conclusions. 6: Catalytic oxidations using cobalt(II) complexes
- L.I. Simandi. 1. Introduction. 2. Cobalt dioxygen complexes. 3. Oxidations catalyzed by Co(salen) complexes. 4. Oxidations catalyzed by cobaloximes. 5. Oxidations catalyzed by cobalt(II) porphyrins. 6. Oxidation weith cobalt(II) phthalocyanines. 7. Oxidations catalyzed by cobalt(II) pyridine complexes. 9. Cobalt-Fenton systems. 10. Co(acac)2 catalyzed oxidations. 11.
「Nielsen BookData」 より