Carbanion chemistry : structures and mechanisms
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Bibliographic Information
Carbanion chemistry : structures and mechanisms
American Chemical Society , Oxford University Press, 2003
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Includes bibliographical references and indexes
Description and Table of Contents
Description
Carbanion Chemistry: Structures and Mechanisms explores the chemistry of these important anionic organic intermediates which are central to organic synthetic reactions from the aldol, Knoevenangel and Claisen condensations to enolate and other carbanion alkylations. Written for researchers and graduate students in organic chemistry, the approach is to consider the basics of carbanion structure, including stereochemistry, the influence of counterions and
aggregation, as well as the substituent effects on stability and reactivity so as to explore the full range of behaviour of these species. Chapters on the spectroscopy of the arylmethyl carbanions and on carbanion reactions promoted by alkaline solids highlight specific areas and will be of interest to
practising physical and synthetic organic chemists and chemical engineers who seek low- or no-solvent "green chemistry" ideas.
Table of Contents
- Preface
- 1. Carbon acidity and carbanions
- 2. Stability of carbanions
- 3. Stereochemistry of carbanions
- 4. Spectroscopy of carbanions
- 5. Heterogenous carbanion reactions catalyzed by solid bases
- 6. Enolates
- 7. Carbanion rearrangements
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