Synthesis and properties of silicones and silicone-modified materials
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Bibliographic Information
Synthesis and properties of silicones and silicone-modified materials
(ACS symposium series, 838)
American Chemical Society, c2003
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Developed from a symposium sponsored by the Division of Polymer Chemistry, Inc., at the 221st National Meeting of the American Chemical Society, San Diego, California, April 1-5, 2001.
Includes bibliographical references and index.
Description and Table of Contents
Description
Synthesis and Properties of Silicones and Silicone-Modified Materials includes sections on synthesis, characterization, elastomers and reinforcement, surfaces and interfaces, copolymers, and reinforcing fillers. Synthesis and Properties of Silicones and Silicone-Modified Materials reviews recent academic and technological developments behind silicones and silicone-modified materials.
Table of Contents
- Preface
- 1. Silicones and Silicone-Modified Materials: A Concise Overview
- SYNTHESIS
- 2. Controlled Synthesis of All Siloxane-Functionalized Architectures by Ring-Opening Polymerization
- 3. Novel Methods of Catalyzing Polysiloxane Syntheses
- 4. Anionic Ring-Opening Polymerization of cis-2,4,6-Trimethyl-2',4',6'-triphynel Cyclotrisiloxane (cis-P[3) in Cyclohexane
- 5. Ru-Catalyzed Hydrosilylation Polymerization: An Overview of RuH[2(CO)(PPh[3)[3-Catalyzed Hydrosilylation Copolymerizations of *a,*w-Dihydrido-oligo-dimethylsiloxanes and Polymerizations of *w-Dimethylsilyloxy Ketones
- 6. Synthesis and Characterization of Siloxane-Containing Polymers Obtained by Dehydrocoupling Polymerization
- 7. Synthesis of Linear Copolysiloxanes with Regular Microstructures and Synthesis of Soluble Polysiloxanes with Trifunctional RSiO[3[/[2 (T) or Tetrafunctional SiO[4[/[2 (Q) Units
- 8. Polysiloxanes in Compressed Carbon Dioxide
- CHARACTERIZATION
- 9. Neutron Scattering Studies of Cyclic and Linear Poly(dimethylsiloxanes)
- 10. Photoexcitation and Photoemission Spectra of Phenyl-Substituted Cyclosiloxanes
- 11. Measuring the Size and Shape of Silicones: The Utilization of Chemometrics and Spectroscopy
- 12. Thermally Stable Siloxane Polymers for Gas Chromatography
- ELASTOMERS AND REINFORCEMENT
- 13. The Effect of Thermal Aging on the Non-Network Species in Room Temperature Vulcanized Polysiloxane Rubbers
- 14. Prediction of the Elastomeric Modulus of Poly(dimethylsiloxane) Networks Formed by Endlinking
- 15. Structure-Property Relationships for Poly(dimethylsiloxane) Networks In Situ Filled Using Titanium 2-Ethylhexoxide and Zirconium n-Butoxide
- 16. Modulus Reduction Mechanism of Trimethylsiloxy Silicates in a Polyorganosiloxane
- 17. NMR Spin Relaxation, Self-Diffusion and Viscosity Studies of Poly(dimethylsiloxane)s Blended with Silicate Nanoparticles
- SURFACES AND INTERFACES
- 18. Investigating the Energetics of Bioadhesion on Microengineered Siloxane Elastomers: Characterizing the Topography, Mechanical Properties, and Surface Energy and Their Effect on Cell Contact Guidance
- 19. Exploiting Favorable Silicone-Protein Interactions: Stabilization against Denaturation at Oil-Water Interfaces
- 20. Association of Siloxane Polymeric Surfactants in Aqueous Solution
- COPOLYMERS
- 21. Poly(amidoamine organosilicon) Dendrimers and Their Derivates of Higher Degree of Structural Complexity
- 22. Surfactant Properties of Poly(dimethylsiloxane)-Containing Block Copolymers from Living Radical Polymerization
- 23. Organic-Inorganic Hybrid Materials from Polysiloxanes and Polysilsesquioxanes Using Controlled/Living Radical Polymerization
- 24. Preparation and Properties of Silicone-Urea Copolymers Doped with Cobalt(II) Chloride
- 25. Block and Graft Copolymers Containing Poly(dimethylsiloxane) and Poly(4-vinyl-pyridine) Segments by Free Radical Polymerization
- 26. Poly(dimethylsiloxane)-graft- oligo(hexafluoropropeneoxide) Via Ring-Opening Polymerization
- 27. Silicone Graft Copolymers with Acrylonitrile, Chloroprene, Styrene, Methylmethacrylate, and an Olefin
- 28. Synthesis and Properties of Poly(butylene terephthalate)-Poly (dimethylsiloxane) Block Copolymers
- 29. The Synthesis of Vinyloxyacetate-Siloxane Copolymer and Its Absorption onto E Glass Fibers
- REINFORCING FILLERS
- 30. Silicification and Biosilicification: Part 2. Silicification at pH 7 in the Presence of a Cationically Charged Polymer in Solution and Immobilized on Substrates
- 31. Diffusion-Controlled Titanate-Catalyzed Condensation of Alkoxysilanes in Nonpolar Solvents
- Author Index
- Subject Index
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