Advanced free radical reactions for organic synthesis

書誌事項

Advanced free radical reactions for organic synthesis

Hideo Togo

Elsevier, 2004

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists.

目次

What are free radicals Functional group conversion Intramolecular radical cyclizations Intermolecular radical addition reactions Alkylation of aromatics Intramolecular hydrogen-atom abstraction Synthetic uses of free radicals for nucleosides and sugars: Barton-McCombie reaction Barton decarboxylation reaction with N-hydroxy-2-thiopyridone Free radical reactions with metal hydrides Stereochemistry in free radical reactions Free radicals related to biology Free radicals for green chemistry

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