Structure elucidation by NMR in organic chemistry : a practical guide

著者

書誌事項

Structure elucidation by NMR in organic chemistry : a practical guide

Eberhard Breitmaier

Wiley, c2002

3rd rev. ed

  • cloth : acid-free paper
  • pbk. : acid-free paper

大学図書館所蔵 件 / 全3件

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注記

Includes bibliographical references (p. 250-251) and index

内容説明・目次

巻冊次

cloth : acid-free paper ISBN 9780470850060

内容説明

This book provides a systematic guide to unraveling structural information from the NMR spectra of unknown synthetic and natural compounds.

目次

  • Preface
  • Preface to the First Edition
  • Symbols and Abbreviations
  • 1. SHORT INTRODUCTION TO BASIC PRINCIPLES AND METHODS. Chemical shift. Spin-spin coupling and coupling constants. Signal multiplicity (multiplets). Spectra of first and higher order
  • Chemical and magnetic equivalence
  • Fourier transform (FT) NMR spectra. Spin decoupling.
  • Nuclear Overhauser effect. Relaxation, relaxation times. 2. RECOGNITION OF STRUCTURAL FRAGMENTS BY NMR. Functional groups. Skeletal structure (atom connectivities). Relative configuration and conformation. Absolute configuration. Intra- and intermolecular interactions.
  • Molecular dynamics (fluxionality).
  • Summary.
  • 3. PROBLEMS.
  • 4. SOLUTIONS TO PROBLEMS
  • REFERENCES.Formula index of solutions to problems.Subject Index.
巻冊次

pbk. : acid-free paper ISBN 9780470850077

内容説明

This text provides the graduate student with a systematic guide to unravelling structural information from the NMR spectra of unknown synthetic and natural compounds. A brief introduction gives an overview of the basic principles and elementary instrumental methods of NMR. This is followed by instructional strategy and tactical advice on how to translate spectra into meaningful structural information. The book provides the student with 55 sets of spectra of graduated complexity. These are designed to challenge the student's problem-solving abilities by the introduction of new concepts with each group of problems, followed by possible solutions and full explanations. A formula index of solutions is provided at the end of the text. This third edition, following on from the second (a reprint of the first edition with corrections), presents significant new material. Thus, actual methods of two-dimensional NMR such as some inverse techniques of heteronuclear shift correlation, as well as the detection of proton-proton connectivities and nuclear Overhauser effects are included. To demonstrate the applications of these methods, new problems have replaced those of previous editions.

目次

Preface. Preface to the First Edition. Symbols and Abbreviations. Short Introduction to Basic Principles and Methods. Recognition of Structural Fragments by NMR. Problems. Solutions to Problems. References. Formula Index of Solutions to Problems. Subject Index.

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