Transition metals for organic synthesis : building blocks and fine chemicals

書誌事項

Transition metals for organic synthesis : building blocks and fine chemicals

edited by M. Beller and C. Bolm

Wiley-VCH, c2004

2nd rev. and enl. ed

  • : set
  • v. 1
  • v. 2

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注記

Previous ed.: 1998

内容説明・目次

内容説明

Already in its second edition, here over 70 internationally renowned authors cover the vast range of possible applications for transition metals in industry as well as academia. This two-volume work presents the current state of research and applications in this economically and scientifically important area of organic synthesis as well as for the production of fine chemicals. Over 1,000 illustrations and the balanced presentation allow readers fast access to the thorough compilation of applications, making this an indispensable work for everyone working with such metals whether professionally or engaged in academic research.

目次

Preface.1 General.1.1 Basic Aspects of Organic Synthesis with Transition Metals (Barry M. Trost).1.2 Concepts for the Use of Transition Metals in Industrial Fine Chemical Synthesis (Wilhelm Keim).2 Transition Metal-Catalyzed Reactions.2.1 Hydroformylation: Applications in the Synthesis of Pharmaceuticals and Fine Chemicals (Matthias Beller and Kamal Kumar).2.2 New Synthetic Applications of Tandem Reactions under Hydroformylation Conditions (Peter Eilbracht and Axel M. Schmidt).2.3 Multiple Carbon-Carbon Bond Formations under Hydroformylation Conditions (Peter Eilbracht and Axel M. Schmidt).2.4 Hydrocarboxylation and Hydroesterification Reactions Catalyzed by Transition Metal Complexes (Bassam El Ali and Howard Alper).2.5 The Amidocarbonylation of Aldehydes (Axel Jacobi von Wangelin, Helfried Neumann, Dirk Gordes, and Matthias Beller).2.6 Transition Metal-catalyzed Alkene and Alkyne Hydrocyanations (Albert L. Casalnuovo and T.V. Rajan Babu).2.7 Cyclopropanation (Andreas Pfaltz).2.8 Cyclomerization of Alkynes (H. Bonnemann and W. Brijoux).2.9 Isomerization of Olefin and the Related Reactions (Sei Otsuka and Kazuhide Tani).2.10 Coupling of Aryl and Alkyl Halides with Organoboron Reagents (Suzuki Reaction) (Alexander Zapf).2.11 Transition Metal-Catalyzed Arylation of Amines and Alcohols (Alexander Zapf, Matthias Beller, and Thomas H. Riermeier).2.12 Catalytic Enantioselective Alkylation of Alkenes by Chiral Metallocenes (Amir H. Hoveyda).2.13 Palladium-Catalyzed Olefinations of Aryl Halides (Heck Reaction) and Related Transformations (Matthias Beller, Alexander Zapf, and Thomas H. Riermeier).2.14 Palladium-Catalyzed Allylic Substitutions (Andreas Heumann).2.15 Alkene and Alkyne Metathesis in Organic Synthesis (Oliver R. Thiel).2.16 Homometallic Lanthanoids in Synthesis: Lanthanide Triflate-catalyzed Synthetic Reactions (Sh Kobayashi).2.17 Lanthanide Complexes in Asymmetric Two-Center Catalysis (Masakatsu Shibasaki, Hiroaki Sasai, and Naoki Yoshikawa).2.18 Bismuth Reagents and Catalysts in Organic Synthesis (Axel Jacobi von Wangelin).3 Transition Metal-Mediated Reactions.3.1 Fischer-Type Carbene Complexes (Karl Heinz Dotz and Ana Minatti).3.2 Titanium-Carbene Mediated Reactions (Nicos A. Petasis).3.3 The McMurry Reaction and Related Transformations (Alois Furstner).3.4 Chromium(II)-Mediated and -Catalyzed C-C Coupling Reactions (David M. Hodgson and Paul J. Comina).3.5 Manganese(III)-Based Oxidative Free-Radical Cyclizations (Barry B. Snider).3.6 Titanium-Mediated Reactions (Rudolf O. Duthaler, Frank Bienewald, and Andreas Hafner).3.7 Zinc-Mediated Reactions (Axel Jacobi von Wangelin and Mathias U. Frederiksen).3.8 The Conjugate Addition Reaction (A. Alexakis).3.9 Carbometalation Reactions of Zinc Enolate Derivatives (Daniella Banon-Tenne and Ilan Marek).3.10 Iron Acyl Complexes (Karola Ruck-Braun).3.11 Iron-Diene Complexes (Hans-Joachim Knolker).3.12 Chromium-Arene Complexes (Hans-Gunther Schmalz and Florian Dehmel).3.13 Pauson-Khand Reactions (D. Strubing and M. Beller).Subject Index.

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