Thermodynamic properties of complex fluid mixtures : research report
著者
書誌事項
Thermodynamic properties of complex fluid mixtures : research report
（Deutsche Forschungsgemeinschaft）
Wiley-VCH, c2004
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内容説明・目次
内容説明
A priority programme of the Deutsche Forschungsgemeinschaft (DFG) was conducted to investigate the thermophysical and thermochemical fundamentals relevant for process design in the chemical and petrochemical industry as well as for biotechnological and environmental process sciences. The priority programme comprised 27 projects in which researchers form various disciplines like applied thermodynamics, industrial chemistry, physical chemistry, process sciences, or biotechnology collaborated to solve some of the major problems of modern thermodynamics. The research results are exclusively documented in this book and cover topics like phase equilibrium in chemical reactive mixtures, in aqueous solutions of electrolytes, aqueous two-phase systems and polymer solutions, high pressure fluid phase equilibria, and microemulsion systems. The results contribute to a better understanding of important phase equilibrium phenomena and help to improve process models.
目次
I. Chemical Reactive Systems. 1. Experimental and Theoretical Investigations at the System CH 3 OH + H 2 SO 4 + H 2 O.-- (Matthias Behmann, Sae--Hoon Kim, Hans--Jurgen Kob, and Klaus Lucas). 2. Measurement of Binary Phase Equilibria of Esterification Systems.-- (Marko Tischmeyer and Wolfgang Arlt). 3. Solubility of Carbon Dioxide in Aqueous Alkanolamine Solutions in the Temperature Range 313 to 353 K and Pressures up to 2.7 MPa.-- (Dirk Silkenbaumer, Bernd Rumpf, and Rudiger N. Lichtenthaler). 4. The Influence of NO 2 on Complex Phase and Reaction Equilibria in Wet Flue Gas Cleaning Processes.-- (Mohammad A. Siddiqi, Jens Petersen, and Klaus Lucas). 5. An Infrared Spectroscopic Investigation of the Species Distribution in the System NH 3 + CO 2 + H 2 O.-- (Ute Lichtfers and Bernd Rumpf). II. Associating Mixtures. 6. VLLE for Mixtures of Water and Alcohols: Measurements and Correlations.-- (Frank Gremer, Gerhard Herres, and Dieter Gorenflo). 7. Phase Equilibria in Ternary Systems Containing Phenols, Hydrocarbons, and Water.-- (Jurgen Schmelzer, Klaus Taubert, Antje Martin, Rene Meinhardt, and Jochen Kempe). 8. Influence of Additives on Hydrophobic Association in Polynary Aqueous Mixtures. An NMR Relaxation and Self--Diffusion Study.-- (Manfred Holz and Manghaiko Mayele). III. Aqueous Solutions of Strong Electrolytes. 9. Phase Equilibria of Aqueous Solutions Containing Volatile Electrolytes.-- (Jurgen Zipprian, Nils Elm, and Karlheinz Schaber). 10. Experimental Determination and Prediction of Phase Equilibria in Systems Containing Strong Electrolytes.-- (Magnus Topphoff, Christian Rose, Jorn Kiepe, and Jurgen Gmehling ). 11. Ion Coordination and Thermodynamic Modeling of Molten Salt Hydrate Mixtures.-- (Wolfgang Voigt, Kay Hettrich, and Dewen Zeng). 12. Effects of Salts on Excess Enthalpies of Binary Liquid Mixtures.-- (Peter Ulbig, Thorsten Friese, and Katrin Wagner). 13. Hydrate Equilibria in Aqueous Solutions Containing Inhibitors.-- (Armin M. Rock and Lothar R, Oellrich). IV. Phase Equilibrium of Aqueous Two--Phase Systems. 14. Experimental and Theoretical Investigations on the Precipitation of Polyelectrolytes from Aqueous Solutions by Neutral Polymers.-- (Thomas Grunfelder and Gerd Maurer). 15. Experimental and Theoretical Studies on Partitioning of Native and Unfolded Enzymes in Aqueous Two--Phase Systems.-- (Maria--Regina Kula and Christian Ramsch). 16. Experimental and Theoretical Investigation on the Partitioning of Proteins in Aqueous Two--Phase Systems.-- (Jochen Brenneisen and Gerd Maurer). V. Phase Equilibrium of Polymer Systems. 17. Phase Behavior of Quaternary Polymer Solutions.-- (Claudia Barth--Wiedmann, Matthias Wunsch, and Bernhard Anton Wolf). 18. Calculation of the High Pressure Phase Equilibrium of Mixtures of Ethlene, Poly(ethylene--co--vinylacetate) Copolymers and Vinyl Acetate with a Cubic Equation of State.-- (C. Browarzik, D. Browarzik, and H. Kehlen). 19. Modeling of Copolymer Phase Equilibria Using the Perturbed--Chain SAFT Equation of State.-- (Feelly Tumakaka and Gabriele Sadowski). 20. Cloud Point Pressures of Ethene + Acrylate + Poly(ethene--co--acrylate)Systems.-- (Michael Buback and Markus Busch). 21. Gas Expanded Polymer Solutions.-- (Bernd Bungert and Wolfgang Arlt). 22. Calculation of the Stability and of the Phase Equilibrium on the System Methylcyclohexane + Polystyrene Based on an Equation of State.-- (Dieter Browarzik and Mario Kowalewski). VI. High--Pressure Phase Equilibria. 23. Phase Equilibrium (Solid--Liquid--Gas) in Binary Systems of Poly(ethylene glycols), Poly(ethylene glycol) dimethyl ether with Carbon Dioxide, Propane, and Nitrogen.-- (Eckhard Weidner and Veronika Wiesmet). 24.Measurements and Modeling of High--Pressure Fluid Phase Equilibrium of Systems Containing Benzene Derivatives and CO 2 .-- (Gerd Brunner, Oliver Pfohl, and Stanimir Petkov). VII. Phase Equilibrium in Microemulsion Systems. 25. The Potential of Surfactants Modified Supercritical Fluids for Dissolving Different Classes of Substances.-- (Uta Lewin--KIretzschmar and Peter Harting). 26. Liquid--Liquid Phase Equilibria in Microemulsion Forming Systems Based on Carbohydrate Surfactants.-- (Sabine Enders, Dirk Hantzschel, Heike Kahl, and Konrad Quitzsch). 27. Interactions of Polyelectrolytes and Zwitterionic Surfactants in Aqueous Solution.-- (Heinz Hoffmann, Holger Lauer, and Klaus Redlich).
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