Ruthenium in organic synthesis

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書誌事項

Ruthenium in organic synthesis

Shun-Ichi Murahashi (ed.)

Wiley-VCH, c2004

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内容説明・目次

内容説明

In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)

目次

Introduction Hydrogenation and Transfer Hydrogenation Oxidation Reactions Carbon-Carbon Bond Formations via Ruthenacycle Intermediates Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates Ruthenium-Catalyzed Olefin Metathesis Ruthenium-Catalyzed Cyclopropanation Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates Ruthenium-Catalyzed Reactions via sp C-H, sp2 C-H, sp3 C-H, and C-Halogen Bond Activations Ruthenium Lewis Acid-Catalyzed Reactions Ruthenium-Catalyzed Reactions with CO and CO2 Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes Ruthenium-Promoted Radical Reactions Ruthenium-Catalyzed Bond Cleavage Reactions

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