Spectrometric identification of organic compounds

著者

• Silverstein, Robert Milton
• Webster, Francis X
• Kiemle, David J.

書誌事項

Spectrometric identification of organic compounds

Robert M. Silverstein, Francis X. Webster, David J. Kiemle

Wiley, c2005

7th ed.

注記

Includes bibliographical references and index

内容説明・目次

内容説明

Originally published in 1962, this was the first book to explore teh identification of organic compounds using spectroscopy. It provides a thorough introduction to the three areas of spectrometry most widely used in spectrometric identification: mass spectrometry, infrared spectrometry, and nuclear magnetic resonance spectrometry. A how-to, hands-on teaching manual with considerably expanded NMR coverage--NMR spectra can now be intrepreted in exquisite detail. This book: Uses a problem-solving approach with extensive reference charts and tables. Offers an extensive set of real-data problems offers a challenge to the practicing chemist

目次

• Chapter 1. Mass Spectrometry. 1.1 Introduction. 1.2 Instrumentation. 1.3 Ionization Methods. 1.4 Mass Analyzers. 1.5 Interpretation of El Mass Spectra. 1.6 Mass Spectra of Some Chemical Classes. Chapter 2. Infrared Spectrometry. 2.1 Introduction. 2.2 Theory. 2.3 Instrumentation. 2.4 Sample Handling. 2.5 Interpretations of Spectra. 2.6 Characteristic Group Absorption of Organic Molecules. Chapter 3. Proton Magnetic Resonance Spectrometry. 3.1 Introduction. 3.2 Theory. 3.3 Instrumentation and Sample Handling. 3.4 Chemical Shift. 3.5 Spin Coupling, Multiplets, Spin Systems. 3.6 Protons on Oxygen, Nitrogen, and Sulfur Atoms. Exchangeable Protons. 3.7 Coupling of Protons to Other Important Nuclei (¹⁹F, E, ³¹P, ²⁹Si, and ¹³C. 3.8 Chemical Shift Equivalence. 3.9 Magnetic Equivalence (Spin-Coupling Equivalence). 3.10 AMX, ABX, and ABC Rigid Systems with Three Coupling Constants. 3.11 Confirmationally Mobile, Open-Chain Systems. Virtual Coupling. 3.12 Chirality. 3.13 Vicinal and Geminal Coupling. 3.14 Low-Range Coupling. 3.15 Selective Spin Decoupling. Double Resonance. 3.16 Nuclear Overhauser Effect, Difference Spectrometry, 1H 1H Proximity Through Space. Chapter 4. Carbon-13 NMR Spectrometry. 4.1 Introduction. 4.2 Theory. 4.3 Interpretation of a Simple ¹³C Spectrum: Diethyl Phthalate. 4.4 Quantitative ¹³C Analysis. 4.5 Chemical Shift Equivalence. 4.6 DEPT. 4.7 Chemical Classes and Chemical Shifts. Chapter 5. Correlation NMR Spectrometry
• 2-D NMR. 5.1 Introduction. 5.2 Theory. 5.3 Correlation Spectrometry. 5.4 Ipsenol: ¹H-¹H COSY. 5.5 Caryophyllene Oxide. 5.6 ¹³C-¹³C Correlations: Inadequate. 5.7 Lactose. 5.8 Relayed Coherence Transfer: TOCSY. 5.9 HMQC - TOCSY. 5.10 ROESY. 5.11 VGSE. 5.12 Gradient Field NMR. Chapter 6. NMR Spectrometry of Other Important Spin 1/2 Nuclei. 6.1 Introduction. 6.2 ¹⁵N Nuclear Magnetic Resonance. 6.3 ¹⁹F Nuclear Magnetic Resonance. 6.4 ²⁹Si Nuclear Magnetic Resonance. 6.5 ³¹P Nuclear Magnetic Resonance. 6.6 Conclusion. Chapter 7. Solved Problems. 7.1 Introduction. Chapter 8. Assigned Problems. 8.1 Introduction.

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詳細情報

• NII書誌ID(NCID): BA70759535
• ISBN:
  • 9780471393627
• 出版国コード: us
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Hoboken, N.J.
• ページ数/冊数: x, 502 p.
• 大きさ: 29 cm