Relaxometry of water-metal ion interactions
著者
書誌事項
Relaxometry of water-metal ion interactions
(Advances in inorganic chemistry / editors, H.J. Emelélus, A.G. Sharpe, v. 57)
Elsevier Academic Press, c2005
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Water interacts with metal ions in a variety of contexts: from aqueous solutions of inorganic salts to enzymatic catalysis. The investigation of water-metal ion interactions is conveniently performed through water 1H NMR at different magnetic field - a technique known as relaxometry. "Advances in Inorganic Chemistry, Volume 57" focuses on relaxometry of water-metal ion interactions. Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry. This is another welcomed addition to the widely acclaimed series, "Advances in Inorganic Chemistry".
目次
Introduction: general theory and nuclear relaxation. NMR relaxation in solution of paramagnetic complexes. 1H NMRD profiles of paramagnetic complexes and metalloproteins. Gd(III)-based contrast agents for MRI. Relaxation by metal containing nano systems. Magnetic relaxation dispersion in porous and dynamically heterogeneous. Water and proton exchange processes on metal ions. Nuclear magnetic relaxation studies on actinide ions and models of actinide complexes. Technical aspects of fast field cycling.
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