Nuclear spin relaxation in liquids : theory, experiments, and applications
著者
書誌事項
Nuclear spin relaxation in liquids : theory, experiments, and applications
（Series in chemical physics, 2）
Taylor & Francis, c2006
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注記
Includes bibliographical references and index
内容説明・目次
内容説明
Nuclear magnetic resonance (NMR) is widely used across many fields because of the rich data it produces, and some of the most valuable data come from the study of nuclear spin relaxation in solution. While described to varying degrees in all major NMR books, spin relaxation is often perceived as a difficult, if not obscure, topic, and an accessible, cohesive treatment has been nearly impossible to find.
Collecting relaxation theory, experimental techniques, and illustrative applications into a single volume, this book clarifies the nature of the phenomenon, shows how to study it, and explains why such studies are worthwhile. Coverage ranges from basic to rigorous theory and from simple to sophisticated experimental methods, and the level of detail is somewhat greater than most other NMR texts. Topics include cross-relaxation, multispin phenomena, relaxation studies of molecular dynamics and structure, and special topics such as relaxation in systems with quadrupolar nuclei and paramagnetic systems.
Avoiding overly demanding mathematics, the authors explain relaxation in a manner that anyone with a basic familiarity with NMR can follow, regardless of their specialty. The focus is on illustrating and explaining the physical nature of the phenomena, rather than the intricate details. Nuclear Spin Relaxation in Liquids: Theory, Experiments, and Applications forms useful supplementary reading for graduate students and a valuable desk reference for NMR spectroscopists, whether in chemistry, physics, chemical physics, or biochemistry.
目次
Equilibrium and Nonequilibrium States in NMR
Simple Relaxation Theory
Relaxation through Dipolar Interactions
The Redfield Relaxation Theory
Applications of Redfield Theory to Systems of Spin 1/2 Nuclei
Spectral Densities and Molecular Dynamics
NMR - the Toolbox
Measuring T1 and T2
Relaxation Times
Cross-Relaxation Measurements
Cross-Correlation and Multiple-Quantum Relaxation Measurements
Relaxation and Molecular Dynamics
Applications of Relaxation-Related Measurements to Structure Determination
Relaxation and Chemical Exchange
Effects of Quadrupolar Nuclei
Nuclear Spin Relaxation in Paramagnetic Systems in Solution
Nuclear Spin Relaxation in Other Aggregation States
Index
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