Organic synthesis : state of the art

著者

• Taber, D. F. (Douglass F.)
• Lambert, Tristan

書誌事項

Organic synthesis : state of the art

Douglass F. Taber

Wiley-Interscience, c2006-

• 2003-2005
• 2005-2007
• 2007-2009
• 2009-2011
• 2011-2013
• 2013-2015
• 2015-2017

注記

Authors of 2011-2013: Douglass F. Taber and Tristan Lambert

Publisher of 2007-2009-: Oxford University Press

Publisher of 2015-2017: Sheridan Books

Includes indexes

内容説明・目次

巻冊次

2013-2015 ISBN 9780190646165

内容説明

Organic synthesis is a vibrant and rapidly evolving field; chemists can now cyclize alkenes directly onto enones. Like the first five books in this series, Organic Synthesis: State of the Art 2013-2015 will lead readers quickly to the most important recent developments in a research area. This series offers chemists a way to stay abreast of what's new and exciting in organic synthesis. The cumulative reaction/transformation index of 2013-2015 outlines all significant new organic transformations over the past twelve years. Future volumes will continue to come out every two years. The 2013-2015 volume features the best new methods in subspecialties such as C-O, C-N and C-C ring construction, catalytic asymmetric synthesis, selective C-H functionalization, and enantioselective epoxidation. This text consolidates two years of Douglass Taber's popular weekly online column, "Organic Chemistry Highlights" as featured on the organic-chemistry.org website and also features cumulative indices of all six volumes in this series, going back twelve years.

目次

Preface Organic Functional Group Interconversion and Protection 1. Organic Functional Group Interconversion 2. Organic Functional Group Interconversion 3. Organic Functional Group Interconversion 4. Oxidation 5. Functional Group Oxidation and Reduction 6. Oxidation of Organic Functional Groups 7. New Methods for Reduction and for Oxidation 8. Reductions 9. Reduction of Organic Functional Groups 10. Organic Functional Group Protection 11. Organic Functional Group Protection and Deprotection 12. Organic Functional Group Protection 13. Functional Group Protection: The Pohl Synthesis of b-1,4-Mannuronate Oligomers Flow Methods 14. Flow Chemistry: The Direct Production of Drug Metabolites 15. Developments in Flow Chemistry 16. Flow Chemistry C-H Functionalization 17. Selective Functionalization of C-H Bonds 18. C-H Functionalization: The Snyder Synthesis of (+)-Scholarisine A 19. C-H Functionalization: The Maimone Synthesis of Podophyllotoxin 20. C-H Functionalization: The Shaw Synthesis of E-d-Viniferin Carbon-Carbon Bond Construction 21. C-C Bond Construction: The Zhu Synthesis of Goniomitine 22. C-C Bond Construction: The Kingsbury Synthesis of (-)-Dihydrocuscohygrine 23. C-C Bond Construction: The Galano Synthesis of 8-F3t-Isoprostane 24. C-C Bond Construction: The Hou Synthesis of (-)-Brevipolide H Reactions of Alkenes 25. Alkenes 26. Alkene Reactions: The Xu/Loh Synthesis of Vitamin A1 27. Reactions of Alkenes 28. Reactions of Alkenes: The Usami Synthesis of (-)-Pericosine E Enantioselective Construction of Acyclic Stereogenic Centers 29. Construction of Single Stereocenters 30. Enantioselective Synthesis of Alcohols and Amines: The Zhu Synthesis of (+)-Trigonoliimine A 31. Enantioselective Synthesis of Alcohols and Amines: The Kim Synthesis of (+)-Frontalin 32. Enantioselective Synthesis of Alcohols and Amines: The Doi Synthesis of Apratoxin C 33. Construction of Alkylated Stereocenters 34. Enantioselective Construction of Alkylated Centers: The Rawal Synthesis of (+)-Fornicin C 35. Alkylated Stereogenic Centers: The Jia Synthesis of (-)-Goniomitine 36. Construction of Alkylated Stereogenic Centers: The Zhu Synthesis of (-)-Rhazinilam 37. Construction of Multiple Stereocenters 38. Arrays of Stereogenic Centers: The Yadav Synthesis of Nhatrangin A 39. Arrays of Stereogenic Centers: The Thomson Synthesis of (-)-Galcatin 40. Arrays of Stereogenic Centers: The Shin/Chandrasekhar Synthesis of (+)-Lactacystin Construction of C-O Rings 41. C-O Ring Construction. The Martin and Martin Synthesis of Teurilene 42. C-O Ring Formation 43. C-O Ring Construction: The Tong Synthesis of (-)-Aculeatin A 44. C-O Ring Construction: The Smith Synthesis of (+)-18-epi-Latrunculol A 45. C-O Ring Construction: The Oger/Lee/Galano Synthesis of 7(RS)-ST-D8-11-dihomo-Isofuran 46. C-O Ring-Containing Natural Products: Cyanolide A (Krische), Bisabosqual A (Parker), Iso-Eriobrucinol A (Hsung), Trichodermolide A (Hiroya), Batrachotoxin Core (Du Bois) 47. Total Synthesis of C-O Natural Products 48. C-O Natural Products: DihomoIsoF (Lee/Galano), Pyrenolide D (Gracza), Clavilactone A (Li), Psoracorylifol A (Tong), Bermudenynol (Kim), Aspercyclide C (Hirama) 49. C-O Ring Construction: Sauropus hexoside (Xie/Wu), (+)-Ipomeamarone (Usuki), Decytospolide A (Fujioka), Cytospolide P (Goswami), (+)-Didemniserinolipid B (Tong), Gymnothelignan N (She) 50. C-O Ring Containing Natural Products: (+)-Isatisine A (Panek), Cephalasporolide E (Sartillo-Piscil), (+)-Xestodecalactone (Jennings), Colchilomycin B (Banwell), Lactimidomycin (Georg), 5,6-Dihydrocineromycin B (Furstner) Construction of C-N Rings 51. C-N Ring Construction: The Waser Synthesis of Jerantinine E 52. C-N Ring Construction: The Glorius Synthesis of ent-Monomorine 53. C-N Ring Construction: The Weinreb Synthesis of Myrioneurinol 54. C-N Ring Construction: The Hattori Synthesis of (+)-Spectaline 55. Alkaloid Synthesis: (-)-L-Batzellaside A (Toyooka), Limazepine A (Zemribo), (+)-Febrifugine (Pansare), Amathaspiramide F (Tambar), Allomatrine (Brown), Lyconadine C (Waters), Tabersonine (Andrade) 56. Alkaloid Synthesis: Penaresidin A (Subba Reddy), Allokainic Acid (Saicic), Sedacryptine (Rutjes), Lepistine (Yokoshima/Fukuyama), Septicine (Hanessian), Lyconadin C (Dai) 57. Alkaloid Synthesis: Indolizidine 223AB (Cha), Lepadiformine (Kim), Kainic Acid (Fukuyama), Gephyrotoxin (Smith), Premarineosin A (Reynolds) 58. Alkaloid Synthesis: (-)-a-Kainic Acid (Ohshima), Serpentine (Scheidt), (-)-Galanthamine (Jia), (+)-Trigolutes B (Gong), Sarain A (Yokoshima/Fukuyama), DZ-2384 (Harran) Substituted Benzene Derivatives 59. Preparation of Benzene Derivatives: The Yu/Baran Synthesis of (+)-Hongoquercin A 60. Substituted Benzenes: The Garg Synthesis of Tubingensin A 61. Substituted Benzenes: The Li Synthesis of Rubriflordilactone A 62. Preparation of Substituted Benzenes: The Beaudry Synthesis of Arundamine Heteroaromatic Derivatives 63. Preparation of Heterocycles: The Boukouvalas Synthesis of (-)-Auxofuran 64. Heteroaromatic Synthesis: The Tokuyama Synthesis of (-)-Rhazinilam 65. Heteroaromatics: The Zhou/Li Synthesis of Goniomitine 66. Heteroaromatic Construction: The Li Synthesis of Mycoleptodiscin A Organocatalyzed C-C Ring Construction 67. Organocatalyzed C-C Ring Construction: The Carreira Synthesis of (+)-Crotogoudin 68. Organocatalyzed C-C Ring Construction: The Jorgenson Synthesis of (+)-Estrone 69. Organocatalyzed C-C Ring Construction: The Bradshaw/Bonjoch Synthesis of (-)-Cermizine B 70. Organocatalyzed C-C Ring Construction: The Mihovilovic Synthesis of Piperenol B Metal-Mediated C-C Ring Construction 71. Metal-mediated C-C Ring Construction: The Carreira Synthesis of (+)-Asperolide C 72. Metal-Mediated C-C Ring Construction: The Sun/Lin Synthesis of Huperzine A 73. Metal-Mediated C-C Ring Construction: The Ding Synthesis of (-)-Indoxamycin B 74. Metal-Mediated C-C Ring Construction: The Lei Synthesis of (-)-Huperzine Q Intermolecular and Intramolecular Diels-Alder Reactions 75. Diels-Alder Cycloaddition: Pancratistatin (Cho), Reddy (Nootkatone), Zhang/Lee (Platensimycin), Nakada (Scabronine G), Isoglaziovianol (Trauner) 76. Diels-Alder Cycloaddition: Fawcettimine (Zhai), Sculponeatin N (Zhai), Elansolid B1 (Kirschning), Frondosin A (Wright), Kingianin H (Parker), Rufescenolide (Snyder) 77. Diels-Alder Cycloaddition: Nicolaioidesin B (Coster), Lycorine (Cho), Bucidarasin A (Nakada), Maoecrystal V (Thomson), Kuwanon J (Wulff/Lei), Vinigrol (Kaliappan) 78. Diels-Alder Cycloaddition: Sarcandralactone A (Snyder), Pseudopterosin (-)-G-J aglycone (Paddon-Row/Sherburn), IBIR-22 (Westwood), Muironolide A (Zakarian), Platencin (Banwell), Chatancin (Maimone) Stereocontrolled C-C Ring Construction 79. Other Methods for C-C Ring Construction: Pinolinone (Bach), Agelastatin A (Batey), Panaginsene (Lee), Salvileucalin D, Salvileucalin C (Ding), ent-Codeine (Hudlicky), Walsucochin B (Xie/Shi) 80. Carbocyclic Ring Construction: The Nicolaou Synthesis of Myceliothermophin E Classics in Total Synthesis 81. The Inoue Synthesis of 19-Hydroxysarmentogenin 82. The Nakada Synthesis of (+)-Ophiobolin A 83. The Herzon Synthesis of (-)-Acutumine 84. The Njardarson Synthesis of Vinigrol 85. The Gin Synthesis of Neofinaconitine 86. The Li Synthesis of Daphenylline 87. The Baran Synthesis of Ingenol 88. The Furstner Synthesis of Amphidinolide F 89. The Deslongchamps Synthesis of (+)-Cassaine 90. The Kan Synthesis of the Streptomyces Alkaloid SB-203207 91. The Trost Synthesis of (-)-Lasonolide A 92. The Fukuyama Synthesis of (-)-Lepenine 93. The Smith Synthesis of (-)-Calyciphylline N 94. The Paterson Synthesis of (-)-Leiodermatolide 95. The Fuwa Synthesis of Didemnaketal B 96. The Lee Synthesis of (-)-Crinipellin A 97. The Snyder Synthesis of Psylloborine A 98. The Morken Synthesis of (+)-Discodermolide 99. The Trauner Synthesis of (-)-Nitidasin 100. The Hoveyda Synthesis of Disorazole C1 101. The Smith Synthesis of (-)-Nodulisporic Acid D 102. The Sato/Chida Synthesis of Paclitaxel (Taxol (R)) 103. The Johnson Synthesis of Paspaline 104. The Ding Synthesis of Steenkrotin A

巻冊次

2007-2009 ISBN 9780199764549

内容説明

Organic synthesis is a vibrant and rapidly evolving field; we can now cyclize amines directly onto alkenes. Like the first two books in this series, Organic Synthesis: State of the Art 2003-2005 and Organic Synthesis: State of the Art 2005-2007, this reference leads readers quickly to the most important recent developments. Two years of Taber's popular weekly online column, "Organic Chemistry Highlights", as featured on the organic-chemistry.org website, are consolidated here, with cumulative indices of all three volumes in this series. Important topics that are covered range from powerful new methods for C-C bond construction to asymmetric organocatalysis and direct C-H functionalization. This go-to reference focuses on the most important recent developments in organic synthesis, and includes a succinct analysis of the significance and applicability of each new synthetic method. It details and analyzes more than twenty complex total syntheses, including the Sammakia synthesis of the Macrolide RK-397, the Ley synthesis of Rapamycin, and the Kobayashi synthesis of (-)-Norzoanthamine.

目次

Table of Contents Organic Functional Group Interconversion and Protection C-H Functionalization Alkene and Alkyne Metathesis Enantioselective Construction of Acyclic Stereogenic Centers Construction of C-O Rings Construction of C-N Rings Substituted Benzene Derivatives Heteroaromatic Derivatives Organocatalyzed C-C Ring Construction Transition Metal Catalyzed C-C Ring Construction Intermolecular and Intramolecular Diels-Alder Reactions Stereocontrolled C-C Ring Construction Classics in Total Synthesis

巻冊次

2009-2011 ISBN 9780199965724

内容説明

Organic synthesis is a vibrant and rapidly evolving field; we can now cyclize amines directly onto alkenes. Like its predecessors, this reference leads readers quickly to the field's more important recent developments. Two years of Douglass F. Taber's popular weekly online column, "Organic Chemistry Highlights", as featured on the organic-chemistry.org website, are consolidated here, with cumulative indices of all three volumes in this series. Important topics that are covered range from powerful new methods for C-C bond construction to asymmetric organocatalysis and direct C-H functionalization. This go-to reference focuses on the most important recent developments in organic synthesis, and includes a succinct analysis of the significance and applicability of each new synthetic method.

目次

• Organic Functional Group Interconversion and Protection
• 1. Best Synthetic Methods: Functional Group Transformations May 17, 2010
• 2. Functional Group Transformations : The Castle Synthesis of Celogentin C October 25, 2010
• 3. Organic Functional Group Conversion March 28, 2011
• 4. Advances in Organic Functional Group Transformation May 16, 2011
• 5. Organic Functional Group Transformation October 31, 2011
• 6. Best Synthetic Methods: Reduction February 22, 2010
• 7. Best Synthetic Methods: Oxidation March 8, 2010
• 8. Best Synthetic Methods: Oxidation and Reduction May 24, 2010
• 9. Oxidation and Reduction May 23, 2011
• 10. Organic Functional Group Protection March 15, 2010
• 11. Functional Group Protection: The Kraus Synthesis of Bauhinoxepin J September 13, 2010
• 12. Functional Group Protection November 8, 2010
• 13. Organic Functional Group Protection September 12, 2011
• 14. Organic Functional Group Protection and Deprotection November 14, 2011
• Flow Methods
• 15. Flow Methods for Organic Synthesis October10, 2011
• C-H Functionalization
• 16. C-H Functionalization: The White Synthesis of 6-Deoxyerythronolide B September 27, 2010
• 17. C-H Functionalization: The Chen Synthesis of Celogentin C March 21, 2011
• 18. Functionalization and Homologation of C-H Bonds September 26, 2011
• Carbon-Carbon Bond Construction
• 19. New Methods for Carbon-Carbon Bond Construction March 22, 2010
• 20. Best Synthetic Methods: C-C Bond Construction May 31 , 2010
• 21. New Methods for C-C Bond Construction February 21, 2011
• 22. New Methods for C-C Bond Construction: The Burke Synthesis of (-)-Peridinin February 28, 2011
• 23. Carbon-Carbon Bond Formation May 30, 2011
• Reactions of Alkenes
• 24. Best Synthetic Methods: Reactions of Alkenes March 29, 2010
• 25. Alkene Reactions: The Dabdoub/Baroni Synthesis of (+-)-Dihydroactinidiolide September 20, 2010
• 26. Reactions of Alkenes March 14, 2011
• 27. Functionalization and Homologation of Alkenes September 19, 2011
• Alkene and Alkyne Metathesis
• 28. Advances in Alkene Metathesis: The Hoveyda Synthesis of (+)-Quebrachamine January 11, 2010
• 29. Alkene and Alkyne Metathesis: Navenone B (Cossy), (+)-Asperpentyn (Daesung Lee), (-)-Amphidininolide K (Eun Lee), Norhalichondrin B (Phillips) January 18, 2010
• 30. Progress in Alkene and Alkyne Metathesis: (+)-5-epi-Citreoviral (Funk) and (+-)-Poitediol (Vanderwal) June 28, 2010
• 31. Alkene and Alkyne Metathesis: Grandisol (Goess), 8-Epihalosilane (Kouklovsky/Vincent), (+)-Chinensiolide B (Hall) January 17, 2011
• 32. Alkene and Alkyne Metathesis: (+)-Anamarine (Sabitha), (+-)-Pseudotabersonine (Martin), Lactimidomycin (Furstner) June 27, 2011
• Enantioselective Construction of Acyclic Stereogenic Centers
• 33. nantioselective Preparation of Alcohols and Amines: The Suh Synthesis of (-)-Macrosphelide J January 25, 2010
• 34. Enantioselective Construction of Alcohols and Amines July 12, 2010
• 35. Construction of Oxygenated and Aminated Stereogenic Centers January 24, 2011
• 36. Enantioselective Preparation of Alcohols and Amines: The Lam Synthesis of (+)-Tanikolide July 11, 2011
• 37. Enantioselective Construction of Alkylated Centers: The Maier Synthesis of Platencin February 8, 2010
• 38. Enantioselective Construction of Alkylated Stereogenic Centers July 19, 2010
• 39. Construction of Alkylated Stereogenic Centers January 31, 2011
• 40. Enantioselective Preparation of Alkylated Stereogenic Centers July 18, 2011
• 41. Construction of Arrays of Stereogenic Centers: The Zhang Synthesis of (+)-Podophyllotoxin February 15, 2010
• 42. Enantioselective Construction of Arrays of Stereogenic Centers: The Breit Synthesis of (+)-Bourgeanic Acid July 26, 2010
• 43. Stereocontrolled Construction of Arrays of Stereogenic Centers: The Mullins Synthesis of (-)-Lasiol February 14, 2011
• 44. Establishing Arrays of Stereogenic Centers: The Sato/Chida Synthesis of (-)-Kainic Acid July 25, 2011
• Construction of C-O Rings
• 45. Stereoselective C-O Ring Construction: The Jamison Synthesis of (-)-Gloeosporone April 12, 2010
• 46. Stereocontrolled Construction of C-O Rings: The Seeberger/Hilvert Synthesis of KDN November 29, 2010
• 47. C-O Ring Construction: The Theodorakis Synthesis of (-)-Englerin April 11, 2011
• 48. Synthesis of Naturally-Occurring Cyclic Ethers: Boivivianin B (Murakami), SC-D13-9-IsoF (Taber), Brevisamide (Panek, Lindsley, Ghosh), Gambierol (Mori) April 19, 2010
• 49. Stereoselective C-O Ring Construction: (+)-Pachastrissamine (Fujii/Ohno), Aspalathin (Minehan), (+)-Varitriol (Ghosh), Aspercyclide A (Spivey), Atnangien (Menche) January 10, 2011
• 50. C-O Ring Construction: (-)-Sclerophytin A (Morken), (+)-Dictyosphaeric Acid (Taylor), Goniothalesdiol (Xie/She), (-)-7-Deoxyloganin (Lupton), (-)-Apicularen A (Uenishi), L-783, 277 (Banwell) April 18, 2011
• Construction of C-N Rings
• 51. Stereocontrolled C-N Ring Construction: The Takayama Synthesis of Lycoposerramine-C April 26, 2010
• 52. Stereocontrolled C-N Ring Construction: The Pyne Synthesis of Hyacinthacine B7 November 15, 2010
• 53. C-N Ring Construciton: The Zakarian Synthesis of (-)-Rhazinilam April 25, 2011
• 54. C-N Ring Construction: The Synthesis of Decursivinme by Mascal and by Jia November 21, 2011
• 55. Alkaloid Synthesis: (S)-Nicotine (Helmchen), (+)-CP-99,994 (Shi), (-)-Adaline (Yu), (-)-Securinine (Bayon/Figueredo), Alkaloid 223A (Aube), (-)-Huperzine A (Fukuyama) May 10, 2010
• 56. Synthesis of C-N Natural Products: (-)-a-Kainic Acid (Helmchen), (+)-Tylophorine (Opatz), (-)-Lycoprine A (Rychnovsky), Fluvirucidine A2 (Suh), Complanidine A (Sarpong) November 22, 2010
• 57. Alkaloid Synthesis: (+)-Preussin (Britton), (+-)-Xenovenine (Livinghouse), (+)-Subincanadine F (Li), (+-)-Strychnine (Reissig), (-)-Virginiamycin M2 (Panek) May 9, 2011
• 58. Alkaloid Synthesis: Mearsine (Taylor), Cephalotaxine (Li), Cocaine (Shing), Quinine (Hatakeyama), Cleavamine (Bennasar), Strychnine (Vanderwal) November 28, 2011
• Substituted Benzene Derivatives
• 59. Benzene Derivatives: The Tanino-Miyashita Synthesis of Zoanthenol June 14, 2010
• 60. Substituted Benzenes: The Saikawa/Nakata Synthesis of Kendomycin October 11, 2010
• 61. Substituted Benzenes: The Kirsch Synthesis of Cybrodol June 13, 2011
• 62. Substituted Benzenes: The Piers/Lau Synthesis of Hamigeran B October 17, 2011
• Heteroaromatic Derivatives
• 63. Heteroaromatic Construction: The Jia Synthesis of (-)-cis-Clavicipitic Acid June 21, 2010
• 64. Heteroaromatics: The Mal Synthesis of Clausevatine D October 18, 2010
• 65. Heteroaromatic Construction: The Fukuyama Synthesis of Tryprostatin A June 20, 2011
• 66. Heteroaromatic Construction: The Wipf Synthesis of Cycloclavine October 24, 2011
• Organocatalyzed C-C Ring Construction
• 67. Organocatalytic Carbocyclic Construction: The Christmann Synthesis of (+)-Rotundial August 16, 2010
• 68. Enantioselective Organocatalytic C-C Ring Construction December 20, 2010
• 69. Organocatalysis of C-C Ring Construction: The MacMillan Synthesis of (+)-Frondosin B August 15, 2011
• 70. Organocatalyzed C-C Ring Construction: The Thomson Synthesis of Streptorububin B December 12, 2011
• Transition Metal Catalyzed C-C Ring Construction
• 71. Metal-Mediated Carbocyclic Construction: The Kobayashi Synthesis of (+)-Fomitellic Acid B August 9, 2010
• 72. Transition-Metal Catalyzed Ring Construction: The Yu Synthesis of a-Agorafuran December 13, 2010
• 73. Metal-Mediated Carbocyclic Construction: The Simpkins Synthesis of Ialibinones A and B August 8, 2011
• 74. Metal Catalyzed C-C Ring Construction: The Nevado Route to (-)-Frondosin A December 19, 2011
• Intermolecular and Intramolecular Diels-Alder Reactions
• 75. Tethered Diels-Alder Cycloadddition: (+-)-Neovibsanin B (Imagawa, Nishizawa), Valerenic Acid (Mulzer), (-)-Himandrine (Movassaghi), (+-)-Pallavicinolide (Wong), (+)-Phomopsidin (Nakada) August 30, 2010
• 76. Intramolecular Diels-Alder Cycloaddition: Brombyin II (Lygo), Ptilocaulin (Livinghouse), Bistellettadine A (Snider), (-)-Pycnanthuquinone C (Trauner), (+)-Caribenol A (Li/Yang) August 29, 2011
• Stereocontrolled C-C Ring Construction
• 77. Carbocyclic Construction: The Deng Synthesis of (-)-Plicatic Acid August 23, 2010
• 78. New Methods for Carbocyclic Construction: The Kim Synthesis of Pentalenene December 27, 2010
• 79. Other Methods for Carbocyclic Construction: The Porco Synthesis of (-)-Hyperibone K August 22, 2011
• 80. Stereoselective Carbocyclic Construction: The Metz Synthesis of (+-)-Codeine December 26, 2011
• Classics in Total Synthesis
• 81. The Williams Synthesis of (-)-4-Hydroxydictyolactone January 4, 2010
• 82. The Nakada Synthesis of (-)-FR182877 February 1, 2010
• 83. The Trost Synthesis of (-)-Pseuodolaric Acid B March 1, 2010
• 84. The Corey Synthesis of (+)-Lupeol April 5, 2010
• 85. The Dixon Synthesis of (-)-Nakadomarin A May 3, 2010
• 86. The Magnus Synthesis of (+-)-Codeine June 7, 2010
• 87. The Nicolaou Synthesis of (+)-Hirsutellone B July 5, 2010
• 88. The Nicolaou Synthesis of (+)-Vannusal August 2, 2011
• 89. The Baran Synthesis of Vinigrol September 6, 2010
• 90. The Overman Synthesis of Briarellin B October 4, 2010
• 91. The Shair Synthesis of Cephalostatin 1 November 1, 2010
• 92. The Chen Synthesis of (-)-Nakiterpiosin December 6, 2010
• 93. The Tanino Synthesis of (-)-Glycinoeclepin A January 3, 2011
• 94. The Boger Synthesis of (-)-Vindoline February 7, 2011
• 95. The Bradshaw/Bonjoch Synthesis of (-)-Anominine March 7, 2011
• 96. The Ma Synthesis of (-)-GB 13 April 4, 2011
• 97. The Trost Synthesis of Bryostatin 16 May 2, 2011
• 98. The Li/Zhang Synthesis of (+-)-Maoecrystal V June 6, 2011
• 99. The Funk Synthesis of (-)-Nakadomarin A July 4, 2011
• 100. The Boger Synthesis of (+)-Complestatin August 1, 2011
• 101. The Overman Synthesis of (-)-Actinophyllic Acid September 5, 2011
• 102. The Tanino/Miyashita Synthesis of Solanoeclepin A October 3, 2011
• 103. The Rawal Synthesis of N-Methylwelwitindolinone D Isonitrile November 7, 2011
• 104. The Garg Synthesis of (+-)-Aspidophylline A December 5, 2011

巻冊次

2003-2005 ISBN 9780470053317

内容説明

The first in a new series, this book provides chemists an effective, much-needed way to stay abreast of recent developments in organic synthesis. The 103 articles review the leading synthetic procedures developed from 2003 - 2005, discussing their significance and their applications. More than 100 reactions are covered, including Heterocycle Construction by Grubbs Metathesis, Enantioselective C-C Bond Construction, and Organic Reactions in Ionic Liquids.

目次

Preface. 1. Transition metal-mediated reactions in organic synthesis. 2. Biotransformations in organic synthesis. 3. Catalytic Enantioselective Synthesis. 4. Enantioselective Synthesis of Borrelidin. 5. Enantioselective Ring Construction. 6. New Routes to Heterocycles. 7. Total Synthesis of the Galbulimima Alkaloid GB 13. 8. Total Synthesis of Ingenol. 9. Best Synthetic Methods: Functional Group Transformations. 10. New Methods for Carbon-Carbon Bond Formation. 11. Mini-Review: Organic Reactions in Ionic Liquids. 12. Adventures in Polycyclic Ring Construction. 13. Synthesis of the Mesotricyclic Diterpenoids Jatrophatrione and Citlalitrione. 14. Best Synthetic Methods: Functional Group Transformations. 15. The Grubbs Reaction in Organic Synthesis. 16. C-N Ring-Forming Reactions by Transition Metal-Catalyzed Intramolecular Alkene Hydroamination. 17. Synthesis of (+)-Phomactin A. 18. Enzymes in Organic Synthesis. 19. Adventures in Polycarbocyclic Construction. 20. Construction of Enantiomerically-Pure Heterocycles. 21. Best Synthetic Methods: Functional Group Transformations. 22. Synthesis of (+)-4,5-Deoxyneodolabelline. 23. New Methods for Carbon-Carbon Bond Formation. 24. Strategies for Enantioselective Synthesis. 25. Preparation of Cyclic Amines. 26. Enantioselective Total Synthesis of (+)-Amphidinolide T1. 27. Stereocontrolled Construction of Carbacycles. 28. "Organometallic" Coupling without the Metal! 29. Preparation of Enantiomerically-Pure Building Blocks. 30. Synthesis of (-)-Strychnine. 31. Pd-Mediated Coupling in Organic Synthesis: Recent Milestones. 32. Enantioselective C-C Bond Construction: Part One of Three. 33. Enantioselective C-C Bond Construction: Part Two of Three. 34. Enantioselective C-C Bond Construction: Part Three of Three. 35. Synthesis of (-)-Podophyllotoxin. 36. The Grubbs Reaction in Organic Synthesis: Part One of Three. 37. The Grubbs Reaction in Organic Synthesis: Part Two of Three. 38. The Grubbs Reaction in Organic Synthesis: Part Three of Three. 39. Synthesis of Deacetoxyalcyonin Acetate. 40. Enantioselective Ring Construction: Part One of Two. 41. Enantioselective Ring Construction: Part Two of Two. 42. Alkyne Metathesis in Synthesis: Syntheses of (+)-Ferrugine and Anatoxin- . 43. Catalytic Asymmetric Synthesis of Quinine and Quinidine. 44. Best Synthetic Methods: Oxidation and Reduction. 45. Best Synthetic Methods: Enantioselective Oxidation and Reduction. 46. Asymmetric Nucleophilic Epoxidation. 47. Asymmetric Synthesis of Nitrogen Heterocycles. 48. Synthesis of Amphidinolide T1. 49. Enantioselective C-C Bond Construction: Part One of Two. 50. Enantioselective C-C Bond Construction: Part Two of Two. 51. Advances in Nitrogen Protection and Deprotection. 52. Enantioselective Synthesis of (+)-Tricycloclavulone. 53. Best Methods for C-C Bond Construction: Part One of Three. 54. Best Methods for C-C Bond Construction: Part Two of Three. 55. Best Methods for C-C Bond Construction: Part Three of Three. 56. Formation of Aromatic-Amino and Aromatic-Carbon Bonds. 57. Synthesis of the Dendrobatid Alkaloid 251F. 58. Enantioselective Construction of Aldol Products: Part One of Two. 59. Enantioselective Construction of Aldol Products: Part Two of Two. 60. Enantioselective -Functionalization of Carbonyl Compounds. 61. Synthesis of (-)-Hamigeran B. 62. Catalytic C-C Bond-Forming Reactions. 63. Rare Sugars are now Readily Available Chiral Pool Starting Materials. 64. Alkyne Metathesis in Organic Synthesis. 65. Total Synthesis of (+/-)-Sordaricin. 66. Ru-Mediated Intramolecular Alkene Metathesis: Improved Substrate and Catalyst Design. 67. Heterocycle Construction by Grubbs Metathesis. 68. Natural Product Synthesis using Grubbs Metathesis: Lasubine II, Ingenol, and Ophirin B. 69. Synthesis of (-)-Tetrodotoxin. 70. Diastereoselective and Enantioselective Construction of Aza- Heterocycles. 71. Diastereoselective and Enantioselective Construction of Cyclic Ethers. 72. Synthesis of Heterocyclic Natural Products: (-)-Ephedradine A, (-)- -Tocopherol, (-)-Lepadin D and (-)-Phenserine. 73. Protection of N- and O-Functional Groups. 74. Synthesis of (-)-Norzoanthamine. 75. Best Synthetic Methods: C-C Bond Formation. 76. Enantioselective Construction of Single Stereogenic Centers. 77. Enantioselective Construction of Arrays of Stereogenic Centers. 78. Synthesis of (-)-Brasilenyne. 79. Best Synthetic Methods: Functional Group Transformations. 80. Enantioselective Construction of Oxygenated and Halogenated Secondary Centers. 81. Enantioselective Construction of Aminated Secondary Centers. 82. Enantioselective Synthesis of the Polyene Antibiotic Aglycone Rimocidinolide Methyl Ester. 83. Enantioselective Transformations of Prochiral Rings. 84. Michael Reactions for Enantioselective Ring Construction. 85. Enantioselective Ring Construction by Intramolecular C-H Insertion and by Cycloaddition. 86. Best Synthetic Methods: Construction of Aromatic and Heteroaromatic Rings. 87. Enantioselective Synthesis of (+)-Epoxomycin. 88. Best Synthetic Methods: Functionalization of Aromatic and Heteroaromatic Rings. 89. Best Synthetic Methods: Oxidation. 90. Enantioselective Allylic Carbon-Carbon Bond Construction. 91. Synthesis of (+)-Cyanthawigin U. 92. Catalysts and Strategies for Alkene Metathesis. 93. N-Heterocycle Construction by Alkene Metathesis. 94. O-Heterocyclic Construction by Alkene Metathesis. 95. Alkene Metathesis in total synthesis: Valienamine, Agelastatin and Tonantzitlolone. 96. Total Synthesis of the Tetracyclines. 97. Enantioselective Construction of N-Heterocycles. 98. Stereocontrolled Construction of Cyclic Ethers. 99. Synthesis of the Proteosome Inhibitors Salinosporamide A, Omuralide and Lactacystin. 100. Synthesis of (-)-Sordaricin. 101. Recent Advances in Carbocyclic Ketone Construction. 102. Stereoselective Construction of Carbocyclic Rings. 103. Asymmetric Transformation of Prochiral Carbocyclic Rings.

巻冊次

2005-2007 ISBN 9780470288498

内容説明

The second volume in a series, Organic Synthesis: State of the Art 2005-2007 will provide you with a convenient, compact summary of the state of the art of organic synthesis. This reference guide will quickly lead you to the most important recent developments like how scientists can now prepare ketones by directly combining aldehydes with terminal alkenes. Inside, you will find detailed analysis of more than twenty total syntheses, including the Davies Synthesis of (-)-Colombiasin A and (-)-Elisapterosin B, the Overman Synthesis of (-)-Sarain A, and the Sorensen Synthesis of (-)-Guanacastepene E.

目次

Preface. 1. Synthesis of (-)- Littoralisone. 2. Enantiocontrolled Construction of Oxygenated and Animated Stereogenic Centers. 3. Catalytic Enantioselective Construction of Alkylated Stereogenic Centers. 4. Catalytic Enantioselective Aldol/Mannich Reactions Leading to Extended Arrays of Stereogenic Centers. 5. Alternative Strategies for the Construction of Extended Arrays of Stereogenic Centers. 6. Synthesis of(-)- Avrainvillamide and (+)- Stephacidin B. 7. Best Synthetic Methods: Oxidation. 8. Best Synthetic Methods: Reduction. 9. Selective Reactions of Alkenes. 10. Synthesis of the Potent FBBP12 Ligand Antascomicin B. 11. Best Synthetic Methods: Carbon-Carbon Bond Formation. 12. Enantioselective Construction of Quaternary Centers. 13. Pd-Mediated Arylation of Aromatic and Hetero Aromatic Rings. 14. The Overman Route to Gelsemine. 15. Stereoselective Construction of Oxygen Heterocycles. 16. Enantioselective Construction of Naturally-Occurring Cyclic Ethers. 17. Stereoselective Construction of Nitrogen Heterocycles. 19. The Stork Synthesis of (-)- Reserpine. 19. Stereocontrolled Construction of Azacyclic Natural Products. 20. Preparation of Benzene Derivatives. 21. Preparation of Heteroaromatics. 22. Preparation and Reactions of Carboxylic Acids, Esters and Amides. 23. The Boger Route to (-)- Vindoline. 24. Protection of C-O and C-N. 25. New Catalysts and Strategies for Alkene Metathesis. 26. Creative Applications of Alkene and Alkyne Metathesis in Total Synthesis: (+)-8epi-Xanthatin, (+)-Longicin, Latrunculin A, and Garsubellin A. 27. Synthesis of Erythronolide A. 28. Best Synthetic Methods: C-C Bond Formation. 29. Catalytic Enantioselective Homologation of Aldehydes to Alcohols and Amines. 30. Catalytic Enantioselective Construction of Alkylated Stereogenic Centers. 31. Enantioselective Construction of Arrays of Stereogenic Centers. 32. Adventures in Complex Indole Synthesis: (-)-Fixherindole I, (+)-Fischerindole G and (+)-Weltwitindolinone A. 33. New Dienes and Dienophiles for Intermolecular and Intramolecular Diels-Alder Cycloaddtions. 34. Organocatalytic Preparation of Enantiomerically-Pure Carbocycles. 35. Carbocycle Construction by the Opening of Strained Rings: Synthesis of Tremulenolide A. 36. The Corey Route to the Dolabellanes: Isoedunol and P-Araneosene. 37. Transition-Metal Catalyzed Enantioselective Ring Construction. 38. Best Synthetic Methods: Functional Group Transformation. 39. Selective Reactions of Alkenes. 40. Synthesis and Absolute Stereochemical Assignment of (-)-Galbulimima Alkaloid 13. 41. Preparation of Benzene Derivatives. 42. Preparation of Heteroaromatic Derivatives. 43. Functional Group Transformation. 44. Functional Group Protection. 45. The Leighton Synthesis of Dolabelide D. 46. Stereocontrolled Construction of N-Heterocycles. 47. Stereocontrolled Construction of O-Heterocycles. 48. Stereocontrolled Synthesis of O-Heterocyclic Natural Products. 49. The Ready Synthesis of (-)-Nigellamine A2. 50. Advances in the Diels-Alder Reaction: Synthesis of (+)-Lycoridine and of Dolabellatrienone. 51. Enantioselective Carbocyclic Construction. 52. Transition Metal Mediated Carbocyclic Construction. 53. Synthesis of (-)-Colombiasin A and (-)-Elisapterosin B. 54. Enantioselective Synthesis of C-N Ring Containing Natural Products. 55. New Catalysts and Strategies for Alkene and Alkyne Metathesis. 56. Heterocyclic Natural Products by Alkene Metathesis. 57. Carbobyclic Natural Products by Alkene Metathesis. 58. The Crimmins Synthesis of (+)-SCH 351448. 59. Enantioselective Construction of Alcohols and Amines. 60. Enantioselective Construction of Alkylated Stereogenic Centers. 61. Enantioselective Construction of Arrays of Stereogenic Centers. 62. The Sorensen Synthesis of (-)-Guanacastepene E. 63. Selective Reactions of Alkenes. 64. Best Synthetic Methods: C-C Bond Formation. 65. Functional Group Protection and Deprotection. 66. The Nicolaou Synthesis of Platensimycin. 67. Stereocontrolled C-O Ring Construction. 68. Stereocontrolled Natural Product Synthesis: Cyclic Ethers and Macrolides. 69. Stereocontrolled C-N Ring Construction. 70. Stereocontrolled Alkaloid Total Synthesis. 71. The Fukuyama Synthesis of Morphine. 73. Oxidation and Reduction in Organic Synthesis. 73. Interconversion of Organic Functional Groups. 74. Best Synthetic Methods: Carbon-Carbon Bond Formation. 75. The Overman Synthesis of (-)-Sarah A. 76. Recent Developments in Alkene Metathesis. 77. Pushing the Limits of Alkene Metathesis in Natural Product Synthesis. 78. Preparation of Benzene Derivatives. 79. The Padwa Synthesis of Aspidophytidine. 80. Synthesis of Heteroaromatics. 8 1. Enantioselective Construction of Alcohols and Amines. 82. Enantioselective Construction of Alkylated Stereogenic Centers. 83. Enantioselective Construction of Arrays of Stereogenic Centers. 84. The Gin Synthesis of Nominine. 85. The Intramolecular Diels-Alder Reaction in Natural Product Synthesis. 86. Catalytic Enantioselective Carbon-Carbon Ring Construction. 87. New Directions in C-C Ring Construction: The Overman Synthesis of Guanacastepene N. 88. The Pettus Synthesis of (+)-Rishirilide B. 89. Selective Reactions of Alkenes. 90. Selective C-H Functionalization. 91. New Methods for Carbon-Carbon Bond Formation. 92. The Nakada Synthesis of (+)-Digitoxigenin. 93. Preparation of Benzene Derivatives. 94. Preparation of Heteroaromatics: The Movassaghi Synthesis of (+)-Chimonanthine. 95. Organic Functional Group Transformation. 96. Organic Functional Group Protection. 97. The Trost Synthesis of (-)-Terpestacin. 98. Stereoselective C-N Ring Construction. 99. Stereoselective C-0 Ring Construction. 100. Synthesis of (-)-Blepharocalyxin D, (-)-Lasonolide A, and Attenol A. 101. The Dark Synthesis of Vigulariol. 102. Enantioselective Organocatalytic Synthesis of Carbocycles: The Iwabuchi Synthesis of (+)-Juvabione. 103. Transition-metal Mediated Synthesis of Carbocycles: The Snapper Synthesis of Pleocarpenone. 104. Enantioselective Construction of Carbocycles: The Williams Synthesis of (+)-Fusicoauritone. 105. C-H Functionalization: The White Reagent. Author Index. Reaction Index.

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詳細情報

• NII書誌ID(NCID): BA79416232
• ISBN:
  • 9780470053317
  • 9780470288498
  • 9780199764549
  • 9780199965724
  • 9780190200794
  • 9780190646165
  • 9780692186848
• 出版国コード: us
• タイトル言語コード: eng
• 本文言語コード: eng
• 出版地: Hoboken, N.J.
• ページ数/冊数: v.
• 大きさ: 25 cm
• 分類:
  • LCC : QD262
  • DC22 : 547/.2
• 件名:
  • LCSH : Organic compounds -- Synthesis -- Research