Ionic liquids in organic synthesis

著者

書誌事項

Ionic liquids in organic synthesis

Sanjay Malhotra, editor ; sponsored by the ACS Division of Organic Chemistry

（ACS symposium series, 950）

American Chemical Society, c2007

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注記

"The chapters in this book are based on papers presented at the special symposium titled Ionic Liquids in Organic Synthesis held at the 228th National Meeting of the American Chemical Society (ACS) at Philadelphia, Pennsylvania during August 24-28, 2004."

Includes bibliographical references and index

内容説明・目次

内容説明

Ionic Liquids in Organic Synthesis brings together leading scientists who have made major contributions to the field of ionic liquids. This book assembles several new methodologies that are interdisciplinary by nature, discussing the unique properties of ionic liquids and the ways in which they induce significant solvent effects on a wide range of pf processes. Twenty-two chapters are included. Ionic Liquids in Organic Synthesis covers areas of rapid progress and industrial importance. Ionic liquids are emerging as novel replacements for volatile organic compounds traditionally used as industrial solvents this book will elaborate on this subject while also examining practical synthetic applications of ionic liquids. This field has been an important topic of research for scientists in both industry and academia over the past 30 years and continues to grow.

目次

  • Preface
  • 1. The Interaction Affecting Organic Reactivity and Selectivity in Ionic Liquids
  • 2. Electrophilic Chemistry in Ionic Liquids
  • 3. Electropolymerization of Benzene in an Ionic Liquid
  • 4. Onium-Poly (Hydrogen Fluorides):Convenient Ionic Liquids for Fluorination and Acid Catalysis
  • 5. Diels-Adler and Friedel-Crafts Reactions in Pyridinium-Based Ionic Liquids
  • 6. Organic Synthesis in Ionic Liquids Utilizing Organometallic Reagents
  • 7. Transition Metal Complexes in Imidazolium Ionic Liquids as Recoverable and Reusable Homogeneous Catalysts
  • 8 Approches to Imino Diels-Adler Reactions in Imidazolium Ionic Liquids Richard Kim
  • 9. Sythesis of Homoallyl Ethers via Allylation of Acetals and Aldehydes in Ionic Liquids
  • 10. Room Temperature Ionic Liquids as Homogeneous Supports for Synthesis
  • 11. Ionic Liquids as a Support of Organic and Inorganic Catalysts
  • 12. Ionic Liquids Applications in Green Chemistry: Copper and Zinc Catalysis
  • 13. Ionic Liquid: A Green Solvent for Organic Transformations I
  • 14. Ionic Liquid: A Green Solvent for Organic Transformations II
  • 15. Ionic Liquids: Neoteric Solvents of Organic and Biocatalytic Transformations
  • 16. Toward Green Processes for Fine Chemcials Synthesis: Biocatalysis in Ionic Liquid-Supercritical Carbon Dioxide Biphasic System
  • 17. Ruthenium Catalyzed Asymmetric Hydrogenation of ?- and ?- Ketoesters in Room Temperature Ionic Liquids Using Chiral P-Phos Ligand
  • 18. Organocatalyzed Asymmetric Michael Reaction in Ionic Liquids-Carbon Dioxide
  • 19. Enantiomerically Pure Thiazolinium and Imidazolium Low Melting Point Salts Prepared for ?-Aminoacids
  • 20. New Cations for Ionic Liquids, Including Chiral Adjuncts with Phosphate and Sulfonylimide Anions
  • 21. Tailoring Adsoprtion-Desorption Properties of Hydroamination Catalysts with Ionic Liquids
  • 22. Synthesis and Application of New Ionic Liquids with Tris(perfluoroalkyl)trifluorophosphate Anions
  • Author Index
  • Subject Index

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