Green chemistry and catalysis

著者

書誌事項

Green chemistry and catalysis

Roger Arthur Sheldon, Isabel Arends and Ulf Hanefeld

(Green chemistry)

Wiley-VCH, c2007

  • : hdk

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: ? Numerous catalytic reductions and oxidations methods ? Solid-acid and solid-base catalysis ? C-C bond formation reactions ? Biocatalysis ? Asymmetric catalysis ? Novel reaction media like e.g. ionic liquids, supercritical CO2 ? Renewable raw materials Written by Roger A. Sheldon -- without doubt one of the leaders in the field with much experience in academia and industry -- and his co-workers, the result is a unified whole, an indispensable source for every scientist looking to improve catalytic reactions, whether in the college or company lab.

目次

INTRODUCTION: GREEN CHEMISTRY AND CATALYSIS E Factors and Atom Efficiency The Role of Catalysis The Development of Organic Synthesis Catalysis by Solid Acids and Bases Catalytic Reduction Catalytic Oxidation Catalytic C-C Bond Formation The Question of Solvents: Alternative Reaction Media Biocatalysis Renewable Raw Materials and White Biotechnology Enantioselective Catalysis Risky Reagents Process Integration and Catalytic Cascades SOLID ACIDS AND BASES AS CATALYSTS Solid Acid Catalysis Solid Base Catalysis Other Approaches CATALYTIC REDUCTIONS Heterogeneous Reduction Catalysts Homogeneous Reduction Catalysts Biocatalytic Reductions CATALYTIC OXIDATIONS Mechanisms of Metal-catalyzed Oxidations Alkenes Alkanes and Alkylaromatics Oxygen-containing Compounds Heteroatom Oxidation Asymmetric Oxidation CATALYTIC CARBON-CARBON BOND FORMATION Enzymes for Carbon-Carbon Bond Formation Transition Metal Catalysis HYDROLYSIS Hydrolysis of Esters Hydrolysis of Amides Hydrolysis of Nitriles CATALYSIS IN NOVEL REACTION MEDIA Two Immiscible Organic Solvents Aqueous Biphasic Catalysis Fluorous Biphasic Catalysis Supercritical Carbon Dioxide Ionic Liquids Biphasic Systems with Supercritical Carbon Dioxide Thermoregulated Biphasic Catalysis CHEMICALS FROM RENEWABLE RAW MATERIALS Carbohydrates Chemical and Chemoenzymatic Transformations of Carbohydrates into Fine Chemicals and Chiral Building Blocks Fats and Oils Terpenes Renewable Raw Materials as Catalysts Green Polymers from Renewable Raw Materials PROCESS INTEGRATION AND CASCADE CATALYSIS Dynamic Kinetic Resolutions by Enzymes Coupled with Metal Catalysts Combination of Asymmetric Hydrogenation with Enzymatic Hydrolysis Catalyst Recovery and Recycling Immobilization of Enzymes EPILOGUE: FUTURE OUTLOOK Green Chemistry: The Road to Sustainability Catalysis and Green Chemistry The Medium is the Message Metabolic Engineering and Cascade Catalysis

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