Recent developments in carbocation and onium ion chemistry

著者

    • Laali, Kenneth K.

書誌事項

Recent developments in carbocation and onium ion chemistry

Kenneth K. Laali, editor

（ACS symposium series, 965）

American Chemical Society, c2007

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

The volume is a collection of 22 chapters written by leading experts and active researchers in the field focusing on various aspects of carbocation and onium ion chemistry. These include stable ion NMR studies, solvolytic and kinetic studies, computational work, and synthetic/preparative aspects.

目次

  • Foreword
  • Preface
  • Chapter 1 Experimental and computational NMR spectroscopic investigation of silyl-substituted carbocations
  • Chapter 2 Super-Stabilization of -Conjugated Cations by Annelation to Bicyclic Frameworks
  • Chapter 3 Unusually Stable Vinyl Cations
  • Chapter 4 Vinyl Iodonium Salts as Precursors to Vinyl Cations
  • Chapter 5 Generation of Alkylideneallyl Cations from Alkylidenecyclopropanone Acetals Selectivity of Reaction with Nucleophiles
  • Chapter 6 Conformational Studies of Cyclobutylmethyl Cations
  • Chapter 7 Persistent Organic Cationic Complexes: Structure and Reactivity
  • Chapter 8 Activation of Electrophilic Sites by Adjacent Cationic Groups
  • Chapter 9 Stabilized Carbocations as Redox Active Chromophores Preparation of Electrochromic Materials Using Stabilized Carbocations
  • Chapter 10 Cation Pool Method and Cation Flow Method
  • Chapter 11 Fluorenylidene and Indenylidene Dications: Insights about Antiaromaticity
  • Chapter 12 Generation, Stability, and Reactions of Alkylated Fullerene Cations
  • Chapter 13 Carbocations on Surfaces
  • FORMATION OF BICYCLOBUTONIUM CATION VIA IONIZATION OF CYCLOPROPYLCARBINYL CHLORIDE OVER NAY ZEOLITE
  • Chapter 14 MO Calculations involving -hydrido cation intermediates relevant to the heptane to toluene dehydrocyclization reaction
  • Chapter 15 Theoretical Studies on Structure and Dynamics of Carbonium Ions
  • Chapter 16 Quantum Chemical Studies of Carbocations from Oxidized Metabolites of Aza-Polycyclic Aromatic Hydrocarbons (Aza-PAHs)
  • Chapter 17 How Does Carbocation Stability Control the Beckmann Rearrangement Reaction?
  • Chapter 18 Solvent Effects on the Chemistry of Bromonium and -Bromo-carbenium Ions as Reactive Intermediates
  • Chapter 19 Syntheses of the CFY2+ (Y = Cl, Br) and CX3+ (X = Cl, Br, OTeF5) Cations Employing the Noble-Gas Oxidant, XeOTeF5+Sb(OTeF5)6?
  • Chapter 20 Organoxenonium Salts
  • SYNTHESIS BY "XENODEBORYLATION", REACTIVITIES, AND NMR SPECTROSCOPIC PROPERTIES
  • Chapter 21 Halogen transfer reactions from bis-amino halonium ions to acceptor olefins: mechanism and strategies for chiral halogenation
  • Chapter 22 Synthesis of Phosphonium Salts by Metal-Catalyzed Addition Reaction

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