Metal vinylidenes and allenylidenes in catalysis : from reactivity to applications in synthesis

書誌事項

Metal vinylidenes and allenylidenes in catalysis : from reactivity to applications in synthesis

edited by Christian Bruneau and Pierre Dixneuf

Wiley-VCH, c2008

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Focusing on preparation and applications in synthesis and catalysis, this book finally closes a gap in the literature by summarizing this hot topic for the first time. As such, it gathers in one volume the key features of metal vinylidene and allenylidene complexes as well as reactive species and covers applications in metathesis, polymerization, molecular materials, carbon rich compounds and fine chemical production. The emphasis here is on the selective transformations of alkynes and enynes plus simple and complex molecules containing a triple C-C bond. The result is a must-have ready reference for organic, catalytic, complex, theoretical and polymer chemists, as well as those working with/on organometallics.

目次

Preparation and stoichiometric reactivity of metal vinylidenes complexes Preparation and stoichiometric reactivity of metal allenylidenes complexes Preparation and reactivity of higher metal cumulenes Theoretical aspects of metal vinylidene and allenylidene complexes Anti-Markovnikov additions of nucleophiles to triple bonds (C-O, C-N, C-P, C-C dimerization) Group 6 metal vinylidenes in catalysis (Cr, Mo, W) Ruthenium vinylidenes and allenylidenes in catalysis for carbocyclization Allenylidene binuclear complexes in catalysis Ruthenium vinylidenes and allenylidenes precursors for olefin metathesis Metal vinylidenes in metathesis polymerization

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詳細情報

  • NII書誌ID(NCID)
    BA87759289
  • ISBN
    • 9783527318926
  • LCCN
    2008428764
  • 出版国コード
    gw
  • タイトル言語コード
    eng
  • 本文言語コード
    eng
  • 出版地
    Weinheim
  • ページ数/冊数
    xvii, 338 p.
  • 大きさ
    25 cm
  • 分類
  • 件名
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