Experiments in green and sustainable chemistry

著者
書誌事項

Experiments in green and sustainable chemistry

edited by Herbert W. Roesky and Dietmar K. Kennepohl ; with a foreward by Jean-Marie Lehn

Wiley-VCH, c2009

  • : hard

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注記

Includes bibliographical references and index

内容説明・目次

内容説明

Encouraging a new attitude and approach to chemistry, this is the first such collection designed for lab courses and experimental teaching. Experts from around the globe present over 40 real-life teaching experiments, all clearly structured and divided into the five main principles of sustainable and green chemistry: catalysis, solvents, high yield and one-pot synthesis, limiting waste and exposure, as well as special topics. With a foreword by Nobel prize winner Jean Marie Lehn.

目次

PART I: CATALYSTS Clean Friedel-Crafts Acylation Knoevenagel Condensation Copper-Catalyzed Arylation of Thiols in Water 2-(2'Anilinyl)-4,4-Dimethyl-2-Oxazoline A Carbene Transfer Agent Enantioselective Organocatalytic Synthesis of Porpionic Acid Ethyl Esters Solid Acid-Catalyzed Electrophilic Annelations Hetergeneous Catalytic Domino Reactions Chemoselective Synthesis of Acylals from Aldehydes The Effect of a Catalyst on the Reaction of Hydroxybenzaldehyde with Acetic Anhydride Renewable Chemicals by Sustainable Oxidation Using Gold Catalysts Sustainable Ruthenium-Catalyzed Direct Arylations Through C-H Bond Functionalizations PART II: SOLVENTS Diaryl Disulfides from Thiols in Water-Ammonia Electrochemical Synthesis of Polypyrrole Employing Green Chemistry Principles Ammonia-Sensing Cyanoaurate Coordination Polymers Green Lab - Aqueous Biphasic Systems for Liquid-Liquid Separations Clean, Fast Palladium-Catalyzed Reactions Using Microwave Heatin and Water as a Solvent Ionic Liquids as Benign Solvents for Sustainable Chemistry Olefin Self-Cross Metatehsis in Ionic Liquids Experiments with Ionic Liquids PART III: HIGH YIELD AND ONE-POT SYNTHESES Efficient Synthesis of Aluminium Complexes Quantitative Synthesis of a Neutral Hexacoordinate Phosphorus Compound Encapsulated Silicon in Haxacoordination Domino Reactions for the Efficient Synthesis of Natural Products Heterocyclic Phosphenium Salts Methyltitanium Triisopropoxide Click Chemistry Synthesis and Recycling of Six Nickel Complexes PART IV: LIMITING WASTE AND EXPOSURE Disposal of Sodium and Potassium Residues Juglone Fluor Retard Dicopper(I) Oxalate Complexes as Molecular Precursors for Copper Deposition Environmentally Friendly Recycling of Sodium PART V: SPECIAL TOPICS The Light Bulb - On and Off Limewater and Carbon Dioxide - A Light Bulb Turns On and Off Template Synthesis of a Macrobiycyle Dinitrosarcophagine Cyclic Molecular Aluminophosphate Biogas Preparation of Colloidal Cadmium Sulfide Quantum Dot Nanoparticles Dendrimer Construction Three Are Better Than One: Gathering Three Different Metals in the Same Molecule

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