Magnetic isotope effect in chemistry and biochemistry

書誌事項

Magnetic isotope effect in chemistry and biochemistry

Anatoly Buchachenko

Nova Science Publishers, c2009

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注記

Page number "vii" from contents

References: p. 135-140

Index: p. 141-149

内容説明・目次

内容説明

This book describes a new phenomenon of global importance - magnetic isotope effect. In contrast to the well-known classical isotope effect which originates from the difference in chemical reactivity of reagents with light and heavy nuclei, magnetic isotope effect results from the difference in reactivity of reagents with magnetic and nonmagnetic isotopic nuclei. It gives a comprehensive description of the new isotope effect and its exhibition in chemical and biochemical reactions as well as future prospects and potential of the use in biomedicine (in particular, for the stimulation of ATP productions in living organisms by using stable magnetic isotope magnesium-25).

目次

  • Introduction
  • Energy & angular momentum as the reaction controlling factors
  • Spin control of chemical reactions
  • Magnetic isotope effect (MIE)
  • Kinetics of isotope fractionation
  • Physics of the MIE
  • MIE for hydrogen-deuterium dyad
  • 13C MIE: controlling factors
  • Oxygen MIE
  • Silicon MIE
  • MIE for sulphur, germanium & tin nuclei
  • Uranium MIE
  • Mercury MIE
  • Magnesium isotope effects
  • Microwave effects
  • Index.

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